Alignment treatment of liquid crystal display device

ABSTRACT

The liquid crystal display device comprising a pair of substrates with alignment layers formed thereon, and a liquid crystal filled between the substrates. Each pixel has pixel display portions CA, CB and non-display portions DA, EA, DB, EB. The pixel display portions are treated for realizing alignment in a different manner from the non-display portions and the alignment of the pixel display portions is controlled by the alignment of the non-display portions. Moreover, the alignment treatment is executed by the irradiation with ultraviolet rays in an inclined direction.

This is a divisional of application Ser. No. 11/528,817, filed Sep. 28,2006, which is a divisional of application Ser. No. 10/871,449, filedJun. 14, 2004, now U.S. Pat. No. 7,133,099, which is a divisional ofapplication Ser. No. 10/317,792, filed Dec. 12, 2002, now U.S. Pat. No.6,781,656, which is a divisional of application Ser. No. 09/030,410,filed Feb. 25, 1998, now U.S. Pat. No. 6,512,564.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a liquid crystal display device. Moreparticularly, the present invention relates to a technology foralignment-treating the alignment layers of a liquid crystal displaydevice.

2. Description of the Related Art

A liquid crystal display device includes a pair of spaced and opposedsubstrates, an electrode and an alignment layer formed on one substrate,an electrode and an alignment layer formed on the other substrate, and aliquid crystal held between the pair of substrates. The electrode of onesubstrate is formed as a common electrode, and the electrode of theother substrate is formed as pixel electrodes. The pixel electrodes canbe formed together with an active matrix. Either one of the substratesis provided with a black matrix and a color filter.

When the liquid crystal display device is viewed, the portions of pixelelectrodes become bright and dark depending upon the presence andabsence of a voltage. That is, the pixel electrodes define the pixeldisplay portions. The openings of the black matrix are arranged tooverlap the pixel electrodes, and have areas smaller than the areas ofthe pixel electrodes. When the black matrix is provided, therefore, thepixel display portions are defined by the openings of the black matrix.In either case, the portions around the pixel display portions arenon-display portions.

The alignment layers can be grouped into horizontal alignment layers andvertical alignment layers. When the horizontal alignment layers areused, the liquid crystal molecules are oriented nearly parallel to thesurface of the substrate. Upon applying a voltage, therefore, the liquidcrystal molecules are tilted with respect to the surface of thesubstrate. When the vertical alignment layers are used, the liquidcrystal molecules are oriented nearly perpendicularly to the surface ofthe substrate. Upon applying a voltage, therefore, the liquid crystalmolecules are tilted obliquely to the surface of the substrate. Ineither case, the alignment layers are alignment-treated by a processsuch as being rubbed. In the case of a TN-type liquid crystal displaydevice, the liquid crystal twists from one alignment layer toward theother alignment layer. Upon effecting the rubbing, furthermore, theliquid crystal molecules are in a pretilt position with a pretilt anglewith respect to the alignment layer.

In the TN-type liquid crystal display device, as viewed in its assembledstate, the two alignment layers are rubbed in directions forming apredetermined angle (90 degrees) relative to each other, so that theliquid crystal twists from one alignment layer toward the otheralignment layer. Here, when it is regarded that the liquid crystalmolecules are oriented in a plane, by neglecting the twist, the pretiltdirection of the liquid crystal molecules positioned near one alignmentlayer is the same as the pretilt direction of the liquid crystalmolecules positioned near the other alignment layer, whereby the liquidcrystal molecules positioned between the alignment layers are orientedaccording to the pretilt directions of liquid crystal moleculespositioned near the two alignment layers.

If the pretilt direction of the liquid crystal molecules positioned nearone alignment layer is opposite to the pretilt direction of the liquidcrystal molecules positioned near the other alignment layer, theintermediately positioned liquid crystal molecules may not be tilted ina predetermined direction because it is not certain that the liquidcrystal molecules depend on any of the pretilt directions of liquidcrystal molecules positioned near these alignment layers. The state ofalignment becomes a spray-alignment when the pretilt angle of thealignment layer is close to the horizontal alignment, and becomes abend-alignment when the pretilt angle of the alignment layer is higherthan, for example, 30° or is close to the vertical alignment.

However, the assignee as for the present case has proposed the fact thateven when the pretilt direction of the liquid crystal moleculespositioned near one alignment layer is opposite to the pretilt directionof the liquid crystal molecules positioned near the other alignmentlayer, if there is a difference between the pretilt angle of the liquidcrystal molecules near one alignment layer and the pretilt angle of theliquid crystal molecules near the other alignment layer, theintermediate liquid crystal molecules are oriented depending on thepretilt direction of the liquid crystal molecules having a largerpretilt angle (or a smaller pretilt angle). The assignee has utilizedthis fact in the alignment division that will be described below. Whenthe horizontal alignment layers are used, the intermediate liquidcrystal molecules are oriented depending on the pretilt direction of theliquid crystal molecules having a larger pretilt angle. When thevertical alignment layers are used, the intermediately positioned liquidcrystal molecules are oriented depending on the pretilt direction of theliquid crystal molecules having a smaller pretilt angle.

The liquid crystal display device involves a problem of a so-calledvisual angle characteristic in which the display device appears whitishor blackish depending upon the direction from which the display surfaceis viewed. Technology for dividing alignment has been proposed forimproving the problem of the visual angle characteristic. The alignmentdivision consists of dividing a pixel into two domains, so that theliquid crystal molecules positioned between the two alignment layers inone domain are tilted in one direction and the liquid crystal moleculespositioned between the two alignment layers in the other domain aretilted in the other direction. A whitish appearance and a blackishappearance are averaged by the alignment division, and a favorabledisplay is obtained irrespective of the direction from which the displaysurface is viewed. To effect the alignment division, however, thealignment layer must be rubbed for each domain, and the alignment layersmust be rubbed twice using a mask.

U.S. Pat. No. 5,473,455, assigned to the assignee of the present case,discloses various technologies for the alignment division. Aparticularly advantageous technology consists of effecting the alignmentdivision by rubbing each alignment layer once. According to thistechnology for the alignment division, each alignment layer is rubbedand irradiated with ultraviolet rays via a mask. In the portions thatare not irradiated with ultraviolet rays, the liquid crystal moleculesare oriented at a first pretilt angle due to the effect of rubbing. Inthe portions irradiated with ultraviolet rays, the liquid crystalmolecules are oriented at a second pretilt angle which is greater (orsmaller) thus the first pretilt angle. A portion of one alignment layerhaving the first pretilt angle is arranged to be opposed to a portion ofthe other alignment layer having the second pretilt angle. The rubbingof the two alignment layers forms a bend-alignment or a spray-alignment.However, the intermediately positioned liquid crystal molecules areoriented according to the pretilt direction of the liquid crystalmolecules having a particular pretilt angle since there exists adifference between the pretilt angles of the liquid crystal moleculesnear the two alignment layers. The solid portion of the mask and theopening appear alternatingly, and the directions of alignment of theliquid crystal alternate correspondingly.

The liquid crystal display device has pixel display portions andnon-display portions. Here, the pixel display portions and thenon-display portions are rubbed simultaneously. However, JapaneseUnexamined Patent Publication (Kokai) No. 8-152638 proposes an alignmenttreatment in which the anchoring energy for the non-display portions islarger than the anchoring energy for the pixel display portions.According to this publication, in a state where a predetermined voltageis applied, the liquid crystal molecules are easily erected in the pixeldisplay portions but the liquid crystal molecules are less easilyerected in the non-display portions and are not affected by a voltage ofa bus line applied to the non-display portions.

There exists a further problem in rubbing. The rubbing consists ofrubbing the alignment layer with a cloth made of, for example, rayon,but dirt is produced as the cloth is brought into a clean room. Besides,the rubbing generates static electricity which may destroy TFTs(thin-film transistors) in the active matrix. It has therefore beendesired to execute the alignment treatment by, for example, irradiationwith ultraviolet rays instead of rubbing.

U.S. Pat. No. 4,974,941 and Japanese Unexamined Patent Publications(Kokai) No. 6-289374 and No. 8-015681, for example, disclose analignment treatment using polarized ultraviolet rays. According to U.S.Pat. No. 4,974,941, a homogeneously oriented liquid crystal cell ispartly irradiated with polarized ultraviolet rays so that the directionof alignment of the irradiated portion becomes different from theinitial direction of homogeneous alignment. According to JapaneseUnexamined Patent Publications (Kokai) No. 6-289374 and No. 8-015681, amesh-like polymer tissue (PPN) that can be optically oriented isirradiated with perpendicularly polarized ultraviolet rays in order torealize the alignment of the liquid crystal molecules. With this method,however, a problem exists in that polarized ultraviolet rays must beused. A polarizer of the Glen-Taylor type is available for obtaining thepolarized ultraviolet rays. However, the Glen-Taylor type polarizer isobtained by cutting a natural calcite and is not suited for practicaluse. It has therefore been desired to effect the alignment treatment byusing non-polarized ultraviolet rays.

When the pixel display portions of the opposing alignment layers aredifferently oriented, the electric charge remains in large amounts nearone alignment layer when a voltage is applied to a given pixel, whilethe liquid crystal display device is being used, and is then no longerapplied. Even in a state where the voltage is no longer applied, theimage that was previously displayed remains slightly visible due to theresidual electric charge. When the alignment is divided by usingultraviolet rays, in particular, the one alignment layer includes aportion irradiated with ultraviolet rays and the other opposingalignment layer includes a portion that is not irradiated withultraviolet rays. Therefore, a difference develops in the alignmenttreatment between the opposing portions of the two alignment layers, andthe electric charge tends to remain in large amounts near one of thealignment layers.

SUMMARY OF THE INVENTION

It is an object of the present invention to provide a liquid crystaldisplay device which prevents the occurrence of a state where anelectric charge remains in large amounts near one of the opposingalignment layers and the image previously displayed remains slightlysticked, due to the residual electric charge, even after the voltage isno longer applied.

Another object of the present invention is to provide a liquid crystaldisplay device, having divided alignments, which enables the opposingalignment layers to be simultaneously oriented with ease.

A further object of the present invention is to provide a liquid crystaldisplay device in which the alignment treatment can be effected, insteadof rubbing.

A still further object of the present invention is to provide a liquidcrystal display device for which the rubbing can be effected incombination with other alignment treatments.

A liquid crystal display device according to the present inventioncomprises a pair of spaced and opposed substrates, an electrode and analignment layer formed on one substrate, an electrode and an alignmentlayer formed on the other substrate, a liquid crystal filled betweensaid pair of substrates, and means for delimiting pixel display portionsand non-display portions at least partly surrounding said pixel displayportions, wherein said alignment layers are treated for realizingalignment so that the alignment of liquid crystal molecules in saidpixel display portions is controlled by the alignment of liquid crystalmolecules in said non-display portions.

In this constitution, the pixel display portions and the non-displayportions are alignment-treated in a different manner. In the pixeldisplay portions, the opposing alignment layers are alignment-treatedsubstantially in the same manner so that the electric charge will notremain in large amounts near either one of the alignment layers. In thenon-display portions, the display is not affected even though theopposing alignment layers are not alignment-treated in substantially thesame manner. It is, then, made possible to obtain a desired display inthe pixel display portions by controlling the alignment of the liquidcrystal molecules in the pixel display portions by the alignment of theliquid crystal molecules in the non-display portions.

The following constitution can be employed together with thisconstitution.

The alignment of the pixel display portion is different from thealignment of the non-display portion.

The alignment layers are made of a uniform alignment material.

The alignment layers are only rubbed in the pixel display portions, andare rubbed and irradiated with ultraviolet rays in the non-displayportions.

The pixel display portions have at least two domains in which the liquidcrystal molecules are oriented in the directions opposite to each other.

The alignment layers comprise at least two material layers in thenon-display portions.

The non-display portions only are rubbed.

The alignment layers are rubbed in at least two directions in thenon-display portions.

The electrode of one substrate comprises pixel electrodes, the onesubstrate is provided with a black matrix with a black stripe andopenings, and the pixel display portions are defined by the openings ofthe black matrix.

Furthermore, a liquid crystal display device according to the presentinvention comprises a pair of spaced and opposed substrates, anelectrode and an alignment layer formed on one substrate, an electrodeand an alignment layer formed on the other substrate, and a liquidcrystal held between said pair of substrates, wherein said alignmentlayer comprised an alignment layer having a vertically aligning propertyand realizes an alignment with a pretilt angle by the irradiation ofnon-polarized ultraviolet rays in an inclined direction.

According to this constitution, it has been found that the alignmenthaving a pretilt angle can be realized by using a vertical alignmentlayer and by irradiating non-polarized ultraviolet rays, in an inclineddirection, without rubbing.

The following constitution can be adopted together with thisconstitution.

The applied ultraviolet rays contain components having wavelengths equalto or shorter than 280 nm.

The degree of parallelism of ultraviolet rays is within ±10 degrees.

According to the present invention, furthermore, a liquid crystaldisplay device comprises a pair of spaced and opposed substrates, anelectrode and an alignment layer formed on one substrate, an electrodeand an alignment layer formed on the other substrate, and a liquidcrystal held between said pair of substrates, wherein said alignmentlayers are rubbed and are irradiated with ultraviolet rays in aninclined direction.

According to this constitution, a new alignment treatment can beeffected relying on the combination of rubbing and irradiation withultraviolet rays.

The following constitution can be adopted together with thisconstitution.

The alignment layers are uniformly rubbed and are irradiated withultraviolet rays from tilted directions different for each of thedomains.

The applied ultraviolet rays contain components having wavelengthsshorter than 280 nm.

The degree of parallelism of ultraviolet rays is within ±10 degrees.

Furthermore, the present invention provides a liquid crystal displaydevice comprising a pair of spaced and opposed substrates, an electrodeand an alignment layer formed on one substrate, an electrode and analignment layer formed on the other substrate, and a liquid crystal heldbetween said pair of substrates, wherein said alignment layers realizean alignment with a pretilt angle of the liquid crystal moleculesneighboring said alignment layers by the irradiation of ultravioletrays, and said substrates are made of a material that absorbsultraviolet rays irradiated for realizing the alignment.

Moreover, the present invention provides a liquid crystal display devicecomprising a pair of spaced and opposed substrates, an electrode and analignment layer formed on one substrate, an electrode and an alignmentlayer formed on the other substrate, and a liquid crystal held betweensaid pair of substrates, wherein the alignment layer of at least one ofsaid substrates is treated so that the alignment layer is divided into aplurality of parallel extending stripe regions and that the direction ofalignment of liquid crystal molecules in one region is opposite to thedirection of alignment of liquid crystal molecules in the neighboringregions and the direction of alignment is parallel to the stripes.

The present invention further provides a liquid crystal display devicecomprising a pair of spaced and opposed substrates, an electrode and analignment layer formed on one substrate, an electrode and an alignmentlayer formed on the other substrate, a liquid crystal filled heldbetween said pair of substrates, and a plurality of pixels, wherein eachpixel has four different alignment regions, and said four alignmentregions are formed so that the liquid crystal molecules are oriented infour directions at 90 degrees relative to each other.

The present invention further provides a liquid crystal display devicecomprising a pair of spaced and opposed substrates, an electrode and analignment layer formed on one substrate, an electrode and an alignmentlayer formed on the other substrate, and a liquid crystal held betweensaid pair of substrates, wherein said alignment layer is treated torealize an alignment with a pretilt angle by irradiation withultraviolet rays and formed so that one pixel has at least two regionshaving different threshold voltages.

According to this constitution, it is possible to realize the alignmentof the liquid crystal by the irradiation of the ultraviolet rays, whichis the easier means, and without using the rubbing (therefore, withoutthe formation of pit-like rubbing traces which may be caused in thesurface of the alignment layers by rubbing), and it is also possible toform a plurality of regions having different threshold voltages.Accordingly, it is possible to improve the viewing angle characteristicwithout increase in a production cost.

The present invention further provides a liquid crystal display devicecomprising a pair of spaced and opposed substrates, an electrode and analignment layer formed on one substrate, an electrode and an alignmentlayer formed on the other substrate, and a liquid crystal filled betweensaid pair of substrates, wherein said alignment layer is formed so thatone pixel has four regions divided by a crosswise boundary line in whichthe alignments of the liquid crystal are mutually different, and ashading layer is provided to cover the crosswise boundary line.

According to this constitution, it is possible to prevent any occurrenceof extremely bright portions at the crosswise boundary line dividingfour regions.

The present invention further provides a quartered, vertically alignedliquid crystal display device comprising a pair of spaced and opposedsubstrates, an electrode and an alignment layer formed on one substrate,an electrode and an alignment layer formed on the other substrate, aliquid crystal filled between said pair of substrates, and polarizersarranged outside said pair of substrates, wherein said alignment layeris formed so that one pixel has four regions divided by a crosswiseboundary line in which the alignments of the liquid crystal are mutuallydifferent, and said polarizers are arranged in a crossed-Nicolarrangement and in predetermined directions deviated in the range from 5degrees to 20 degrees relative to the vertical direction, the horizontaldirection, and the directions inclined by 45 degrees with respect to thevertical direction and the horizontal direction.

BRIEF DESCRIPTION OF THE DRAWINGS

The present invention will become more apparent from the followingdescription of the preferred embodiments, with reference to theaccompanying drawings, in which:

FIG. 1 is a plan view schematically illustrating a portion of a liquidcrystal display device according to the first embodiment of the presentinvention;

FIGS. 2A to 2C are cross-sectional views illustrating the liquid crystaldisplay device of FIG. 1;

FIG. 3 is a view illustrating an active matrix formed on one substrateof FIGS. 2A to 2C;

FIG. 4 is a cross-sectional view of the liquid crystal display device,for explaining the alignment treatment for the alignment layers of FIG.1;

FIG. 5 is a cross-sectional view of the liquid crystal device of FIG. 4when the voltage is applied;

FIG. 6 is a view illustrating the first stage of behavior of the liquidcrystal molecules in one domain in FIG. 5;

FIG. 7 is a view illustrating the second stage of behavior of the liquidcrystal molecules in FIG. 5;

FIG. 8 is a cross-sectional view of the liquid crystal display devicefor explaining the alignment division;

FIGS. 9A and 9B are views showing visual angle characteristicsaccomplished by the alignment division of FIG. 8;

FIG. 10 is a view illustrating a fundamental example of the alignmentdivision;

FIG. 11 is a view illustrating the alignment treatment for obtaining thealignment division of FIG. 10;

FIG. 12 is a view illustrating another example of the alignmentdivision;

FIG. 13 is a view illustrating the alignment treatment for obtaining thealignment division of FIG. 12;

FIG. 14 is a view of an example for realizing the alignment division ofFIG. 12;

FIGS. 15A to 15C are views of another example for realizing thealignment division of FIG. 12;

FIG. 16 is a cross-sectional view of the liquid crystal display deviceaccording to the second embodiment of the present invention;

FIG. 17 is a view illustrating an apparatus for alignment-treating thealignment layers of FIG. 16;

FIG. 18 is a view illustrating the principle for alignment-treating thealignment layers of FIG. 16;

FIG. 19 is a view simplifying FIG. 18;

FIG. 20 is a view illustrating a modified example of FIG. 18;

FIG. 21 is a view illustrating a spectrum distribution of ultravioletrays used in the apparatus of FIG. 17;

FIG. 22 is a view for alignment-treating the two domains;

FIG. 23 is a view showing the division of alignment accomplished by thealignment treatment of FIG. 22;

FIG. 24 is a view showing a mask for effecting the alignment treatmentof FIGS. 22 and 23;

FIG. 25 is a view illustrating a modified example of FIG. 22;

FIGS. 26A to 26D are views illustrating the third embodiment of thepresent invention;

FIG. 27 is a view illustrating the alignment treatment according to thethird embodiment;

FIG. 28 is a view showing liquid crystal molecules relative to thealignment layers alignment-treated according to the third embodiment;

FIG. 29 is a diagram illustrating the feature of the glass substrate inthe liquid crystal display device of FIG. 16;

FIG. 30 is a comparative view for explaining the feature of FIG. 29;

FIG. 31 is a view illustrating the intensity of the transmitted light ofthe light source when a substrate is used and when no substrate is used;

FIG. 32 is a view illustrating the fourth embodiment of the presentinvention;

FIG. 33 is a view illustrating the liquid crystal molecules that areoriented relative to the alignment layer treated in FIG. 32;

FIG. 34 is a view illustrating a mask used in the alignment treatment ofFIG. 32;

FIG. 35 is a view illustrating a problem caused by a relationshipbetween the mask and the direction of ultraviolet ray projection;

FIG. 36 is a diagram illustrating a relationship between the angle ofirradiation of ultraviolet rays and the realized pretilt angle;

FIG. 37 is a view illustrating the irradiation of ultraviolet rays usingtwo lamps;

FIG. 38 is a view illustrating the irradiation of ultraviolet rays usinga single lamp;

FIG. 39 is a view showing the two alignment layers obtained by theirradiation of ultraviolet rays in FIG. 32, which are so arranged thatthe stripes meet at right angles relative to each other;

FIG. 40 is a view showing the four alignments obtained by thearrangement of FIG. 39;

FIG. 41 is a view showing the two alignment layers obtained by theirradiation of ultraviolet rays in FIG. 32, which are so arranged thatthe stripes are in parallel with each other;

FIG. 42 is a view illustrating an example in which one alignment layeronly is irradiated with ultraviolet rays;

FIG. 43 is a view illustrating a relationship between a pixel and analignment layer having regions alignment-treated in FIGS. 39 and 40;

FIG. 44 is a view illustrating a case where the alignment layer of FIG.43 is deviated relative to the pixel;

FIG. 45 is a view illustrating another relationship between a pixel andan alignment layer having regions alignment-treated in FIGS. 39 and 40;

FIG. 46 is a diagram illustrating a case where the alignment layer ofFIG. 45 is deviated relative to the pixel;

FIGS. 47A and 47B are views illustrating the fifth embodiment of thepresent invention;

FIGS. 48A and 48B are views illustrating the alignment of the liquidcrystal molecules realized when the alignment layer treated according tothe steps of FIGS. 47A and 47B are used;

FIGS. 49A and 49B are views illustrating the alignment layer arrangedopposite to the alignment layer treated according to the steps of FIGS.47A and 47B;

FIGS. 50A and 50B are views illustrating the alignment of the liquidcrystal molecules realized when the alignment layer treated according tothe steps of FIGS. 49A and 49B are used;

FIG. 51 is a view illustrating the alignment of the liquid crystalmolecules in the liquid crystal display device including the alignmentlayers treated according to the steps of FIGS. 47A-47B and 49A-49B;

FIG. 52 is a view illustrating a modified example of the alignmentdivision of FIG. 51;

FIG. 53 is a view illustrating a further example of the alignmentdivision FIG. 51;

FIG. 54 is a view illustrating the relationship between the appliedvoltage and the transmittance of the liquid crystal display device ofFIGS. 47A to 51;

FIG. 55 is a view of a prior art of a threshold division;

FIGS. 56A and 56B are views illustrating a modified example of thealignment treatment;

FIGS. 57A and 57B are views illustrating a further example of thealignment treatment;

FIG. 58 is a view of a further example for irradiating the alignmentlayers with the ultraviolet rays, using a mask;

FIG. 59 is a view illustrating a further example of the alignmenttreatment;

FIG. 60 is a view illustrating the sixth embodiment of the presentinvention;

FIG. 61 is a view illustrating the alignment of the liquid crystal of aportion of one pixel in the liquid crystal display device of FIG. 60;

FIG. 62 is a view illustrating the relationship between the appliedvoltage and the transmittance of the quartered, vertically alignedliquid crystal display device when no storage capacitance electrode isused;

FIG. 63 is a view illustrating the relationship between the appliedvoltage and the transmittance of the liquid crystal display device ofFIG. 60;

FIG. 64 is a view illustrating another example of a shading layer;

FIG. 65 is a view illustrating another example for solving the problemexplained in FIG. 62;

FIG. 66 is a view illustrating the relationship between the appliedvoltage and the transmittance of the liquid crystal display devicehaving the feature of FIG. 65;

FIG. 67 is a view of an example of the liquid crystal display deviceincluding spacers treated for the vertical alignment; and

FIG. 68 is a view of a spacer having no treatment for the verticalalignment.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

FIG. 1 is a plan view schematically illustrating a portion of a liquidcrystal display device according to the first embodiment of the presentinvention, FIGS. 2A to 2C are cross-sectional views illustrating theliquid crystal display device of FIG. 1, and FIG. 3 is a viewillustrating an active matrix formed on one substrate of FIG. 2. Inparticular, FIG. 2A is a cross-sectional view taken along the line 2A-2Ain FIG. 1, FIG. 2B is a cross-sectional view taken along the line 2B-2Bin FIG. 1, and FIG. 2C is a cross-sectional view taken along the line2C-2C in FIG. 1.

In FIGS. 2A to 2C, a liquid crystal display device 10 is constituted bya pair of spaced and opposed transparent glass substrates 12 and 14, anda liquid crystal layer 16 held between these substrates 12 and 14. Onone substrate (lower substrate) 12 are formed transparent pixelelectrodes 18 and a transparent alignment layer 20, and on the othersubstrate (upper substrate) 14 are formed a transparent common electrode22 and a transparent alignment layer 24. The pixel electrodes 18 on thelower substrate 12 are formed together with an active matrix shown inFIG. 3. On the upper substrate 14 are further formed a color filter 26and a black matrix 28. Polarizers 29A and 29B are arranged outside thelower and upper substrates 12 and 14.

Referring to FIG. 3, the active matrix includes gate bus lines 32, drainbus lines 30, and TFTs (thin-film transistors) 34. The TFTs 34 areconnected to the gate bus line 32 and to the drain bus line 30, and arefurther connected to the pixel electrode 18. Alignment division isadopted to the liquid crystal display device 10, and each pixelelectrode 18 is divided into two domains A and B by a line 36 passingnearly through the center of the pixel electrode 18.

In FIGS. 2A to 2C, the color filter 26 includes color elements R, G andB, and the pixel electrodes 18 are arranged in correspondence to thecolor elements R, G and B of the color filter 26. Openings 28 a of theblack matrix 28 are arranged to overlap the pixel electrodes 18. Eachopening 28 a in the black matrix 28 has an area smaller than an area ofthe pixel electrode 18.

Under the pixel electrode 18 is provided a storage capacity electrode 40passing nearly through the center of the pixel electrode 18. The layer27 is an insulating layer. The bus lines 30 and 32, the storage capacityelectrode 40 and the pixel electrodes 18 are electrically separated fromeach other by insulating layers (not shown) disposed between them.

The openings 28 a in the black matrix 28 define pixel display portionsC. The pixel display portions C are surrounded by non-display portionsdefined by black stripes of the black matrix 28. The storage capacityelectrode 40 constitutes a non-display portion E. FIG. 2 also shows twodomains A and B divided by the line 36 passing through the center ofeach of the pixel electrodes 18. The line 36 passes through the centerof the storage capacity electrode 40.

FIG. 1 is a view illustrating one pixel electrode 18 of FIG. 3 and itssurrounding regions, and also illustrates elements of FIGS. 2A to 2C. InFIG. 1 a portion of the domain A of FIGS. 2A to 2C overlapping the pixeldisplay portion C is denoted by CA, a portion of the domain A of FIGS.2A to 2C overlapping the non-display portion D is denoted by DA, and aportion of the domain A of FIGS. 2A to 2C overlapping the non-displayportion E is denoted by EA. Similarly, a portion of the domain B ofFIGS. 2A to 2C overlapping the pixel display portion C is denoted by CB,a portion of the domain B of FIGS. 2A to 2C overlapping the non-displayportion D is denoted by DB, and a portion of the domain B of FIGS. 2A to2C overlapping the non-display portion E is denoted by EB.

In FIG. 1, the pixel display portions CA and CB are represented by whiteareas, and the non-display portions DA, EA, DB and EB are represented byhatched areas. The hatching direction of the non-display portions DA andEA is opposite to the hatching direction of the non-display portions DBand EB, indicating that these portions are oriented in a differentmanner. That is, the pixel display portion C and the non-displayportions D and E are divided into two domains CA, DA, EA: CB, DB, EB bythe center line of the storage capacity electrode 40 and by the centerlines of black stripes of the black matrix 28.

FIGS. 4 and 5 are views illustrating an example of the alignmenttreatment of FIG. 1, wherein FIG. 4 illustrates a state of the liquidcrystal when no voltage is applied, and FIG. 5 illustrates a state ofthe liquid crystal when a voltage is applied. These drawings showalignment layers 20 and 24, but either do not show other pixelelectrodes and the black matrix or show them in a simplified manner.FIGS. 4 and 5 illustrate an example in which the alignment layers 20 and24 are vertical alignment layers. To simplify the illustration, theliquid crystal molecules 16A are all shown in the same plane, neglectingtwist.

One domain A will be described with reference to FIG. 4. The liquidcrystal molecules 16A near the lower alignment layer 20 are pretilted ata small pretilt angle (e.g., 85°) in the non-display portions DA and EA,and are pretilted at a large pretilt angle (e.g., 89°) in the pixeldisplay portion CA. The liquid crystal molecules 16A near the upper,opposing alignment layer 24 are uniformly pretilted at a large pretiltangle (e.g., 89°) in the non-display portions DA, EA and in the pixeldisplay portion CA.

The pretilt direction of the liquid crystal molecules 16A close to thelower alignment layer 20 is opposite to the pretilt direction of theliquid crystal molecules 16A close to the upper alignment layer 24. Inthis example using the vertical alignment layers, the liquid crystal 16as a whole is in a bend-alignment between the lower alignment layer 20and the upper alignment layer 24.

In the pixel display portion CA, the pretilt angle of the liquid crystalmolecules 16A near the lower alignment layer 20 and the pretilt angle ofthe liquid crystal molecules 16A near the upper alignment layer 24 arenearly the same, and are in a bend-alignment. If the pixel displayportion CA of such an alignment is independently present, it is notcertain that the liquid crystal molecules 16A intermediately positionedbetween the upper alignment layer 20 and the lower alignment layer 24are definitely tilted, according to the pretilt angle of the liquidcrystal molecules 16A close to the lower alignment layer 20 or to thepretilt angle of the liquid crystal molecules 16A close to the upperalignment layer 24, when a voltage is applied; i.e., the liquid crystalmolecules 16A are not tilted in a predetermined direction. In order toplace the pixel display portion CA in such an unstable state, it ispossible that the pixel display portion CA is not rubbed.

In the non-display portions DA and EA, on the other hand, the liquidcrystal molecules 16A close to the lower alignment layer 20 arepretilted at a small pretilt angle, and the liquid crystal molecules 16Aclose to the upper alignment layer 24 are pretilted at a large pretiltangle. When the liquid crystal molecules 16A are pretilted at differentpretilt angles close to the upper and lower alignment layers 20 and 24,the liquid crystal molecules 16A intermediately positioned between theupper and lower alignment layers 20 and 24 are tilted according to thealignment of a smaller pretilt angle when a voltage is applied theretothough they may have been in a bend-alignment.

In the non-display portions DA and EA as shown in FIG. 5, when a voltageis applied, the liquid crystal molecules 16A are tilted in the right-endupper direction according to the alignment treatment of the loweralignment layer 20. This state is shown in an exaggerated manner in FIG.6. It is not certain in which direction the liquid crystal molecules 16Aare tilted in the pixel display portion CA. However, the pixel displayportion CA is surrounded by the non-display portions DA and EA.Therefore, the liquid crystal molecules 16A in the pixel display portionCA are controlled by the alignment of liquid crystal molecules 16A inthe non-display portions DA and EA, and are tilted in a direction inwhich the liquid crystal molecules 16A in the non-display portions DAand EA are tilted upon the application of the voltage. This state isshown in FIG. 7 in an exaggerated manner.

Here, what is important is that both the lower alignment layer 20 andthe upper alignment layer 24 are alignment-treated in the same manner inthe pixel display portion CA. When a symmetrical AC voltage is appliedand is then interrupted, therefore, there occurs no difference betweenthe electric charge remaining near the lower alignment layer 20 and theelectric charge remaining near the upper alignment layer 24, making itpossible to prevent the occurrence of sticking of an image. In thenon-display portions DA and EA, there exists a difference between thealignment treatments and there may occur a difference between theresidual electric charges. However, the difference occurring in thenon-display portions does not affect the formation of an image.

The same also holds true in the domain B provided the relationship ofthe alignment between the lower alignment layer 20 and the upperalignment layer 24 is reversed. In FIG. 4, the liquid crystal molecules16A close to the lower alignment layer 20 are uniformly pretilted at alarge pretilt angle (e.g., 89°) in the non-display portions DB, EB andin the pixel display portion CB. The liquid crystal molecules 16A closeto the upper opposing alignment layer 24 are pretilted at a smallpretilt angle (e.g., 85°) in the non-display portions DB and EB, and arepretilted at a large pretilt angle (e.g., 89°) in the pixel displayportion CB.

In this case, too, the pretilt direction of liquid crystal molecules 16Anear the lower alignment layer 20 is opposite to the pretilt directionof liquid crystal molecules 16A near the upper alignment layer 24, andthe liquid crystal layer 16 between the lower alignment layer 20 and theupper alignment layer 24 are in a bend-alignment as a whole.

In the pixel display portion CB, the pretilt angle of the liquid crystalmolecules 16A near the lower alignment layer 20 and the pretilt angle ofthe liquid crystal molecules 16A near the upper alignment layer 24 arenearly the same and are in a bend-alignment. When the pixel displayportion CB of such an alignment is independently present, it is notcertain that the liquid crystal molecules 16A positioned intermediatelybetween the upper alignment layer 20 and the lower alignment layer 24may be tilted according to one of the pretilt angle of the liquidcrystal molecules 16A close to the lower alignment layer 20 or thepretilt angle of the liquid crystal molecules 16A close to the upperalignment layer 24 when a voltage is applied; i.e., the liquid crystalmolecules 16A are not tilted in a predetermined direction.

In the non-display portions DB and EB, on the other hand, the liquidcrystal molecules 16A close to the lower alignment layer 20 arepretilted at a large pretilt angle, and the liquid crystal molecules 16Aclose to the upper alignment layer 24 are pretilted at a small pretiltangle. When the voltage is applied, therefore, the liquid crystalmolecules 16A positioned between the upper and lower alignment layers 20and 24 are tilted according to the alignment of a smaller pretilt angle.

In the non-display portions DB and EB as shown in FIG. 5, therefore,when the voltage is applied, the liquid crystal molecules 16A are tiltedin the right-end lower direction. It is not certain in which directionthe liquid crystal molecules 16A are tilted in the pixel display portionCB by themselves. However, the pixel display portion CB is surrounded bythe non-display portions DB and EB. Therefore, the liquid crystalmolecules 16A in the pixel display portion CB are controlled by thealignment of liquid crystal molecules 16A in the non-display portions DBand EB, and are tilted in a direction in which the liquid crystalmolecules 16A in the non-display portions DB and EB are tilted.

Even in this case, both the lower alignment layer 20 and the upperalignment layer 24 are alignment-treated in the same manner in the pixeldisplay portion CB. When a voltage is applied and then interrupted,therefore, there occurs no difference between the electric chargeremaining near the lower alignment layer 20 and the electric chargeremaining near the upper alignment layer 24, making it possible toprevent the occurrence of printing of image. In the non-display portionsDB and EB, there exists a difference between the alignment treatmentsand there may occur a difference between the residual electric charges.However, the difference occurring in the non-display portions does notaffect the formation of an image.

When the domain A is compared with the domain B, the liquid crystalmolecules 16A in the domain A are tilted in the right-end upperdirection as a whole and the liquid crystal molecules 16A in the domainB are tilted in the right-end lower direction as a whole. This makes itpossible to obtain the effect of the alignment division.

FIGS. 8 and 9A-9B are views illustrating the effect of the alignmentdivision. In FIG. 8, the liquid crystal molecules 16A between the upperand lower alignment layers 20 and 24 are tilted in the right-end upperdirection in the domain A, and the liquid crystal molecules 16A betweenthe upper and lower alignment layers 20 and 24 are tilted in theright-end lower direction in the domain B. This holds true when thehorizontal alignment layers are used and when the vertical alignmentlayers are used. Use of the horizontal alignment layers is differentfrom the use of the vertical alignment layers in the following sense.That is, a small pretilt angle when the vertical alignment layers areused is equivalent to a large pretilt angle when the horizontalalignment layers are used, and the liquid crystal having a dielectricconstant of negative anisotropy is preferred in the case of the verticalalignment layers and the liquid crystal having a dielectric constant ofpositive anisotropy is preferred in the case of the horizontal alignmentlayers.

FIGS. 9A and 9B are views illustrating visual angle characteristics whenthe domain B of FIG. 8 is viewed in the directions of arrows U, N and L.FIG. 9A illustrates the case when the horizontal alignment layers areused, and FIG. 9B illustrates the case when the vertical alignmentlayers are used. Referring, for example, to FIG. 9A, when the domain Bis viewed from the direction of arrow N, the transmission decreases inproportion to an increase in the voltage as represented by a curve N,making it possible to obtain a favorable display. When the domain B isviewed in the direction of arrow U, the transmission sharply drops withan increase in the voltage as represented by a curve U, so that thedisplay becomes blackish. When the domain B is viewed in the directionof arrow L, the transmission does not drop much with an increase in thevoltage as represented by a curve L, and the display becomes whitish. Inthe TN-type liquid crystal display device as described above, theviewing angle characteristics change depending upon the direction inwhich the liquid crystal molecules 16A are tilted (quality of displaychanges depending upon the direction of view).

The direction in which the liquid crystal molecules 16A are tilted inthe domain A is opposite to the direction in which the liquid crystalmolecules 16B are tilted in the domain B and, hence, the viewing anglecharacteristics of the domain A become opposite to the viewing anglecharacteristics of the domain B. That is, the characteristics of thedomain A viewed in the direction of arrow U is the same as thecharacteristics of the domain B viewed in the direction of arrow L.Therefore, the characteristics when the domain A and the domain B aresimultaneously viewed in the direction of arrow U become as representedby a curve I which is obtained by the average of the curves U and L ofFIG. 9A. The characteristics of the curve I approach the characteristicsof the curve N, and a relatively favorable display is obtained no matterfrom which direction it is viewed. This also holds true even in the caseof FIG. 9B.

To effect the alignment division, therefore, the direction in which theliquid crystal molecules 16A, positioned in the middle of the domain A,are tilted should be set to be opposite to the direction in which theliquid crystal molecules 16A, positioned in the middle of the domain B,are tilted. In the constitution of FIG. 1, the non-display regions DAand EA should be so alignment-treated that the direction in which theliquid crystal molecules 16A, in the pixel display region CA, are tiltedis the same as the direction in which the liquid crystal molecules 16A,in the domain A, are tilted and no limitation is imposed on the meansfor alignment treatment. Similarly, the non-display regions DB and EBshould be so alignment-treated that the direction in which the liquidcrystal molecules 16A, in the pixel display region CB, are tilted is thesame as the direction in which the liquid crystal molecules 16A, in thedomain B, are tilted and no limitation is imposed on the means foralignment treatment.

FIGS. 10 and 11 are views illustrating an example of a basic alignmenttreatment for effecting the alignment division. This example employshorizontal alignment layers. The lower alignment layer 20 is rubbed in adirection Ria in the domain A and is rubbed in a direction Rib in thedomain B. The upper alignment layer 24 is rubbed in a direction Roa inthe domain A and is rubbed in a direction Rob in the domain B. Therubbing direction Ria is opposite to the rubbing Rib, and the rubbingdirection Roa is opposite to the rubbing Rob. To effect the rubbing inthe above-mentioned manner, therefore, the alignment layers 20 and 24are rubbed two times using a mask.

Then, in the domain A, the liquid crystals are twisted from the rubbingdirection Ria of the lower alignment layer 20 toward the rubbingdirection Roa of the upper alignment layer 24, and the liquid crystalmolecules 16A positioned between the lower alignment layer 20 and theupper alignment layer 24 are tilted, for example, in the right-end upperdirection as shown in FIG. 10. In the domain B, the liquid crystals aretwisted from the rubbing direction Rib of the lower alignment layer 20toward the rubbing direction Rob of the upper alignment layer 24, andthe liquid crystal molecules 16A positioned between the lower alignmentlayer 20 and the upper alignment layer 24 are oriented, for example, inthe left-end upper direction as shown in FIG. 10.

The above-mentioned alignment treatment can be executed for thenon-display regions DA, EA, DB and EB shown in FIG. 1. The pixel displayregions CA and CB are in a bend-alignment or in a spray-alignment. In anextreme case, the pixel display regions CA and CB may not be subjectedto the alignment treatment such as rubbing or the like, since it ispossible to arrange that it is not certain how the liquid crystalschange in the pixel display regions CA and CB. This tendency isremarkable in the case of vertical alignment layers.

FIGS. 12 and 13 are views illustrating another example of the alignmenttreatment for effecting the alignment division. In FIG. 13, the loweralignment layer 20 is rubbed in the direction Ri in both the domain Aand the domain B, and the upper alignment layer 24 is rubbed in thedirection Ro in both the domain A and the domain B. Referring to FIG.12, the lower alignment layer 20 is alignment-treated so that the liquidcrystal molecules 16A close to the lower alignment layer 20 arepretilted at a large pretilt angle α in the domain B and are pretiltedat a small pretilt angle β in the domain A. The upper alignment layer 24is alignment-treated so that the liquid crystal molecules 16A close tothe upper alignment layer 24 are pretilted at a large pretilt angle α inthe domain A and are pretilted at a small pretilt angle β in the domainB.

In the domains A and B of the opposing alignment layers 20 and 24,therefore, a large pretilt angle α is created near one alignment layerand a small pretilt angle β is created near the other alignment layer.In this case, the intermediate liquid crystal molecules 16A between theopposing alignment layers 20 and 24 are tilted according to the liquidcrystal molecules 16A having a large pretilt angle α. In the domain A,therefore, the intermediate liquid crystal molecules 16A are tilted inthe same direction as that of the liquid crystal molecules 16A near theupper alignment layer 24, and in the domain B, the intermediate liquidcrystal molecules 16A are tilted in the same direction as that of theliquid crystal molecules 16A near the lower alignment layer 20. In thedomains A and B, therefore, the intermediate liquid crystal molecules16A are tilted in the opposite directions to accomplish the alignmentdivision.

The alignment treatment of FIGS. 4 and 5 complies with the treatment foraccomplishing the alignment division of FIGS. 12 and 13. The differenceis simply whether the horizontal alignment layers are used or thevertical alignment layers are used. The above-mentioned alignmenttreatment is executed for the non-display regions DA, EA, DB and EB ofFIG. 1, and the pixel display regions CA and CB are in a bend-alignmentor spray-alignment.

FIG. 14 is a view illustrating a means for realizing different pretiltangles α and β of FIG. 12. In this example, the alignment layer 20 isformed by two alignment layers 20A and 20B, and the alignment layer 24is formed by two alignment layers 24A and 24B. The upper alignmentlayers 20B and 24B are patterned depending upon the sizes of the domainsA and B, permitting the lower alignment layers 20A and 24A to be exposedthrough the openings. In the domain A, the alignment layer 20A and thealignment layer 24B are opposed to each other and in the domain B, thealignment layer 20B and the alignment layer 24A are opposed to eachother.

The alignment layers 20B and 24B are made of a material of which theliquid crystal molecules 16A are oriented at a pretilt angle α uponpredetermined rubbing, and the alignment layers 20A and 24A are made ofa material of which the liquid crystal molecules 16A are oriented at apretilt angle β upon similar rubbing. That is, different pretilt anglesα and β are realized by using different alignment materials. Therefore,the alignments of FIG. 12 are obtained when the alignment layers 20 and24 constituted as shown in FIG. 14 are rubbed as shown in FIG. 13.

FIGS. 15A to 15C illustrate another means for realizing the differentpretilt angles α and β of FIG. 12. In this example, the alignment layers20 and 24 are formed of uniform alignment layers, but are irradiatedwith ultraviolet rays to change the pretilt angles. Referring to FIG.15A, the whole surface of the alignment layer 20(24) is rubbed by arubbing roll 50. Referring to FIG. 15B, the alignment layer isirradiated with ultraviolet rays (UV), using a mask 52 having openings52 a. Referring to FIG. 15C, when the rubbed alignment layer 20(24) ispartly irradiated with ultraviolet rays, the liquid crystal molecules16A are pretilted at a pretilt angle α in the portion where thealignment layer 20(24) is irradiated with ultraviolet rays, and theliquid crystal molecules 16A are pretilted at a pretilt angle B in theportion where the alignment layer 20(24) is not irradiated withultraviolet rays. The pretilt angle α is smaller than the pretilt angleβ in both cases where the vertical alignment layers are used and thehorizontal alignment layers are used.

FIG. 16 is a view illustrating the second embodiment of the presentinvention. Like the embodiment of FIG. 2, the liquid crystal displaydevice 10 comprises a pair of spaced and opposed transparent glasssubstrates 12 and 14 and a liquid crystal layer 16 held between thesesubstrates 12 and 14. On one substrate 12 are formed transparent pixelelectrodes 18 and a transparent alignment layer 20, and on the othersubstrate 14 are formed a transparent common electrode 22 and atransparent alignment layer 24. On the upper substrate 14 are furtherformed a color filter 26 and a black matrix 28. The color filters 26include color elements R, G and B. There is further provided a storagecapacity electrode 40. The alignment layers realize alignments withpretilt angles, which are established without rubbing.

FIG. 17 illustrates an apparatus 60 for alignment-treating the alignmentlayer 20(24). The apparatus 60 for alignment treatment includes a sourceof light 62 for irradiating non-polarized ultraviolet rays, a mirror 64,and a holder 66 for supporting the substrate 12(14) provided with thealignment layer 20(24). The holder 66 supports the substrate 12(14) atan angle of 45 degrees with respect to the optical axis. In other words,parallel ultraviolet rays from the source of light 62 are made incidentto the alignment layer 20(24) at an angle of 45.

The source of light 62 includes a parabolic reflector 62 a and emitsgenerally parallel non-polarized ultraviolet rays. FIG. 21 shows apreferred spectral distribution of the source of light 62. The spectraldistribution has a peak near the wavelength 250 nm. It is desired thatthe emitted ultraviolet rays contain components having wavelengthsshorter than 280 nm. The alignment layer 20(24) treated by the apparatus60 for alignment treatment is a vertical alignment layer having avertical aligning property, and realizes alignment with a pretilt angleby the irradiation of non-polarized ultraviolet rays in an inclineddirection.

The alignment layer 20(24) is a vertical alignment layer having avertical aligning property in a state where it is applied and baked, andan example of the structure thereof is described below.

FIG. 18 is a view illustrating the principle of alignment treatment, andFIG. 19 is a simplified view of the view of FIG. 18. The alignment layer20(24) represented by the above chemical formula has alkyl groups Rwhich realize the vertical aligning property. In FIG. 18, the alkylgroups R are denoted by a reference numeral 70. It is considered thatthe alkyl groups 70 protrude in random from the surface of the alignmentlayer 20(24).

The ultraviolet rays 68 are irradiated obliquely to the alignment layer20(24) along the azimuth X, and the pretilt direction (azimuth line) ofthe liquid crystal is parallel to the azimuth of the direction ofincidence of the ultraviolet rays 68. The non-polarized ultraviolet rays68 contain polarized light of P wave and S wave, but the S wave does notcontribute to the directivity of alignment. That is, the S wave exhibitsno action in the X-direction but exhibits an action in the Y-direction.The action in the Y-direction, however, has the same magnitude in thepositive direction and in the negative direction of the Y-axis, and doesnot contribute to the directivity of alignment.

The P wave acts upon a portion including alkyl groups 70 in a planewhich is parallel to the direction of incidence of the ultraviolet rays68, and affects the directivity of alignment. FIG. 19 illustrates aplane parallel to the direction of incidence of the ultraviolet rays 68,i.e., illustrates a portion of FIG. 18 along the plane parallel to theoscillation plane of the P waves. In FIG. 19, the alkyl groups 70 can begrouped into two components that are inclined in opposite directionswith respect to the direction of oscillation of the P wave of theultraviolet rays 68. The components in the alkyl groups 70 “a” areinclined so that they are nearly perpendicular to the direction ofoscillation of the P wave, and the components “b” are inclined so thatthey are nearly horizontal to the direction of oscillation of the Pwave. It is not generally considered that the alkyl groups are destroyedby ultraviolet rays. It can be rather considered that the portionssupporting the alkyl groups or the portions tilting the alkyl groups,are destroyed by ultraviolet rays. The portions “a” (corresponding tothe components “a”) tilting the alkyl groups to be nearly perpendicularto the direction of oscillation of the P wave and the portions “b”(corresponding to the components “b”) tilting the alkyl groups to benearly parallel to the direction of oscillation of the P wave, aredestroyed at different ratios by the ultraviolet rays. The portions “b”tilting the alkyl groups easily receive energy and are easily destroyedby the energy of ultraviolet rays. Therefore, the components “b”decrease by the irradiation of the ultraviolet rays, whereas thecomponents “a” remain without being destroyed. When the alignment layer20(24) is used in the liquid crystal display device 10, therefore, theliquid crystal molecules are pretilted according to the components “a”of the alkyl groups 70 of the alignment layer 20(24).

FIG. 20 is a view illustrating a modified example of FIG. 19. In FIG.19, it was presumed that the components “a” and “b” of the alkyl groups70 received the action of ultraviolet rays uniformly. FIG. 20, however,illustrates the case where portions aa and bb of components “a” and “b”of the alkyl groups 70 receive the action of ultraviolet raysparticularly strongly. These portions aa and bb are bent in the oppositedirections relative to most of the portions of components “a” and “b” ofthe alkyl groups 70.

Therefore, the portions aa are easily destroyed by the energy ofultraviolet rays, but the portions bb are less easily destroyed by theenergy of ultraviolet rays. Therefore, the components “b” having portionbb remain. When the alignment layer 20(24) is used in the liquid crystaldisplay device 10, therefore, the liquid crystal molecules are pretiltedaccording to the inclination of the components “b” of the alkyl groups70 of the alignment layer 20(24). In the cases of FIGS. 19 and 20, itcan be proved that the liquid crystal molecules are aligned at apredetermined pretilt angle. By using the vertical alignment layers,therefore, an alignment having a pretilt angle is realized by theirradiation with non-polarized ultraviolet rays in an inclineddirection, without rubbing.

In FIGS. 19 and 20, however, it is sometimes difficult to determinewhich one of the component “a” or the component “b” will be easilydestroyed, before the irradiation of ultraviolet rays. Upon irradiationwith ultraviolet rays in an inclined direction, however, one of thecomponent “a” or the component “b” is destroyed, and the other oneremains, whereby the liquid crystal molecules are aligned at a pretiltangle, without rubbing.

The alignment treatment is conducted under the following conditions. Thematerial of the vertical alignment layer 20(24) is, for example, RN722,RN783, or RN784 sold by Nissan Kagaku Co., or JALS-204 produced byNippon Synthetic Rubber Co. First, a material of the alignment layer isapplied to the substrate 12(14) by spin-coating at 2000 rpm. Thethickness of the alignment layer is about 80 nm. The film is baked at180° C. for two hours. Next, the alignment layer is irradiated withultraviolet rays, using the apparatus 60 for alignment treatment shownin FIG. 17. The source of light 62 is a deep UV irradiation devicemanufactured by Ushio Denki Co. In this source of light 62, the portionemitting the ultraviolet rays has a size of about 5 mm, and nearlyparallel ultraviolet rays are obtained by the reflector 62 a. Theultraviolet rays are projected over a range of from one minute to 30minutes to prepare several samples, which are used to assemble liquidcrystal display devices. The liquid crystal molecules are pretilted inthe liquid crystal display devices having samples irradiated for notshorter than 10 seconds, and the pretilted angle decreases from 90degrees, i.e., in the vertical direction, to 88 degrees.

The spectral distribution shown in FIG. 21 contains components havingwavelengths near 250 nm which work effectively. Thus, a lamp of theshort arc-type is used as the source of light, ultraviolet rays havingwavelengths of near 250 nm are chiefly used and the degree ofparallelism of ultraviolet rays is set to be smaller than ±10 degrees,and preferably smaller than ±3 degrees, using a reflector. Tests areconducted using a source of light having a spectral distribution shownin FIG. 21 and by using ultraviolet rays emitted by the same source oflight with the components having wavelengths of longer than 300 nm arecut, and the results are compared. It is confirmed that the liquidcrystal molecules are pretilted in the same manner. From the results, itis learned that irradiation with ultraviolet rays having wavelengthsshorter than 280 nm is effective in realizing the pre-tilt the verticalalignment layer 20(24).

According to this embodiment as described above, the vertical alignmentlayer 20(24) can realize the pretilt, using non-polarized ultravioletrays. It can be said that the P wave only is practically effective inthe non-polarized ultraviolet rays. Still, the possibility of usingnon-polarized ultraviolet rays has great merit. It has heretofore beenproposed to develop the pretilt by irradiating the horizontal alignmentlayers with polarized ultraviolet rays. In this case, however, thepretilt cannot be developed by using non-polarized ultraviolet rays.Therefore, it becomes necessary to use a polarizer for obtainingpolarized ultraviolet rays. At present, such a polarizer is availableonly as the Glen-Taylor type. The Glen-Taylor type polarizer, however,is produced by cutting natural calcite which is not suited for practicaluse. Therefore, the alignment treatment using non-polarized ultravioletrays does not require any polarizer for ultraviolet ray irradiation, andis very desirable.

In this embodiment, the non-polarized ultraviolet rays are uniformlyprojected onto the whole surface of the vertical alignment layer 20(24).To effect the alignment division, therefore, the divided domains A and Bare irradiated with ultraviolet rays 68A and 68B in the oppositedirections as shown in FIG. 22. Then, as shown in FIG. 23, there areobtained two domains A and B in which the intermediately positionedliquid crystal molecules are tilted in the opposite directions. In thiscase, there is no difference in the pretilt angle of the liquid crystalmolecules between the two domains A and B.

FIG. 24 illustrates an example in which the domains A and B aresimultaneously irradiated with ultraviolet rays 68A and 68B in theopposite directions. In this case, a mask 74 having openings 74A isused. Ultraviolet rays 68A and 68B enter one opening 74A in oppositedirections. Here, ultraviolet rays 68A and 68B entering in the oppositedirections are just aimed at the two domains A and B under the followingconditions. When a pitch of the opening 74A of the mask 74 (pitch of apixel) is denoted by P, a distance between the mask 74 and the alignmentlayer 20(24) is denoted by Q, and an angle of incidence of ultravioletrays 68A and 68B is denoted by θ, then, a relation Q=(P/4) sin θ ismaintained.

By applying this principle, ultraviolet rays can be simultaneouslyprojected in four directions as shown in FIG. 25 in order to form fourdifferent domains Aa, Ab, Ba and Bb.

FIGS. 26A to 26D are views illustrating the alignment treatmentaccording to the third embodiment of the present invention. Thealignment layer 20(24) shown here can be used in the liquid crystaldisplay device shown in FIG. 16. Referring to FIG. 26A, the wholesurface of the alignment layer 20 is rubbed with a rubbing roll 50, sothat the liquid crystal molecules 16A are pretilted in a predeterminedmanner as shown in FIG. 26B. Referring to FIG. 26C, non-polarizedultraviolet rays 68A, 68B are projected in the opposite directions.Then, as shown in FIG. 26D, the realized pretilt angles in the domains Aand B are the sums of a pretilt angle due to rubbing and pretilt anglesdue to irradiation with ultraviolet rays. Accordingly, a differenceexists between the pretilt angles of the liquid crystal molecules in thetwo domains A and B.

The ultraviolet rays are irradiated in the manner described above. Alamp of the short arc-type is used as a source of light, ultravioletrays of shorter than 280 nm and, preferably, around 250 nm are chieflyused, and the degree of parallelism of ultraviolet rays is set to besmaller than ±10 degrees, and preferably smaller than ±3 degrees, byusing a reflector. A polyimide exhibiting a vertically oriented propertyis used as alignment layers.

Referring to FIG. 27, the other alignment layer 24 is rubbed andirradiated with ultraviolet rays in the same manner. The two alignmentlayers 20 and 24 are rubbed in the directions as shown in, for example,FIG. 13. When the liquid crystal display device is assembled, using thealignment layers 20 and 24, there are obtained two domains A and B inwhich the intermediately positioned liquid crystal molecules are tiltedin the opposite directions as shown in FIG. 28 to accomplish thealignment division. In this case, the alignment layers 20 and 24 havebeen rubbed and irradiated with ultraviolet rays on the whole surfacesthereof, and there is no difference in the alignment treatment betweenthe opposing alignment layers 20 and 24 unlike the case when theultraviolet rays are locally projected by using the mask 52 as describedwith reference to FIG. 15. When the alignment treatment is carried outaccording to FIGS. 26 to 28, therefore, there is no need to effect theseparate treatment, for the pixel display portions and the non-displayportions, that was done in FIG. 1.

In the alignment treatment according to FIGS. 16 to 24, no rubbing iseffected. When the liquid crystal molecules are pretilted at a smallpretilt angle upon irradiation with ultraviolet rays without effectingthe rubbing, the rubbing is effected in combination with the irradiationof ultraviolet rays, as in this embodiment, in order to obtain asufficiently large pretilt angle yet to maintain the effects of theexamples of FIGS. 16 to 24.

FIG. 29 is a view illustrating a feature of the glass substrates 12 and14 of the liquid crystal display device of FIG. 16. Referring to FIG.29, the glass substrates 12 and 14 are made of a material which absorbsultraviolet rays irradiated for realizing the alignment.

FIG. 29 illustrates the case where the alignment layer 20(24) isirradiated with ultraviolet rays. The ultraviolet rays 68 are projectedin a state where the glass substrate 12(14) provided with the alignmentlayer 20(24) is supported on a sample plate 76. In this case, the glasssubstrate 12(14) absorbs ultraviolet rays 68; i.e., ultraviolet rays 68falling on the alignment layer 20(24) are absorbed by the glasssubstrate 12(14) after having passed through the alignment layer 20(24).

FIG. 30 illustrates the case where the glass substrate 12(14) is made ofa material that does not absorb ultraviolet rays 68 and the alignmentlayer 20(24) is irradiated with ultraviolet rays 68. The ultravioletrays 68 are projected in a state where the glass substrate 12(14)provided with the alignment layer 20(24) is supported on the sampleplate 76. In this case, the ultraviolet rays 68 falling on the alignmentlayer 20(24) pass through the alignment layer 20(24) and, then, throughthe glass substrate 12(14), are reflected by the surface of the sampleplate 76, and pass again through the glass substrate 12(14) and thealignment layer 20(24).

In this case, the P wave of ultraviolet rays 68 falling on the alignmentlayer 20(24) oscillates in a direction connecting the left-end upperside to the right-end lower side in FIG. 30, whereas the P wave ofultraviolet rays 68 reflected by the surface of the sample plate 76 andare passing through the alignment layer 20(24) oscillates in a directionconnecting the left-end lower side to the right-end upper side in FIG.30. This is equal to the case where the alignment layer 20(24) isirradiated in the oppositely inclined directions (without mask).

As described with reference to FIGS. 18 to 20, the alignment is realizedas either the components “a” or the components “b” of the alkyl groups70, tilted in the opposite directions, being destroyed by the P wave ofultraviolet rays 68 that is incident in the inclined direction. When thelight reflects as shown in FIG. 30, e.g., when the P wave of theincident ultraviolet ray 68 destroys the components “a”, then, the Pwave of the reflected ultraviolet ray 68 destroys the components “b”.After all, the alkyl groups 70 are all destroyed, and there remains noalkyl group 70 standing obliquely, and the alignment action is notobtained or the alignment is disturbed.

As shown in FIG. 29, therefore, it is arranged that the glass substrate12(14) absorbs no ultraviolet rays 68, and that the incident ultravioletrays 68 are absorbed by the glass substrate 12(14) after acting upon thealignment layer 20(24), so that the ultraviolet rays 68 are reflected byneither the sample plate 76 under the glass substrate nor the interfacebetween the glass substrate 12(14) and the air. As explained withreference to FIG. 30, therefore, it is arranged that the reflectedultraviolet rays do not act upon the alignment layer 20(24) in order toreliably reform the alignment by the irradiation with ultraviolet rays.

FIG. 31 is a view illustrating the ultraviolet rays (light from a sourceof light) used and the feature of the glass substrate, wherein blackbars represent the intensity of ultraviolet rays when no substrate(plate) is used, and white bars represent the intensity of ultravioletrays when a substrate (plate) is used (light passes through thesubstrate). As the black bars indicate, the source of light that is usedemits the strongest ultraviolet rays in the wavelength regions near 250nm and 300 nm. The glass substrate 12(14) is the one that absorbsultraviolet rays in these wavelength regions. As the white barsindicate, ultraviolet rays of around 300 nm or shorter are cut off whenthe light passes through the glass substrate 12(14). Peaks at around 250nm disappear, too. The transmission of ultraviolet rays shown in FIG. 29is thus confirmed.

As the alignment layer 20(24), use is made of, for example, RN-722,RN-783 or RN-784 marketed by Nissan Kagaku Co. First, the alignmentlayer 20(24) is applied onto the glass substrate 12(14) by spin-coatingat 2000 rpm. The alignment layer 20(24) has a thickness of about 80 nm.This is fired at 180° C. for two hours. Then, ultraviolet rays areprojected by using a deep UV irradiation device manufactured by UshioDenki Co. In this ultraviolet ray irradiation device, the portionemitting ultraviolet rays has a size of about 5 mm. By establishing anoptical system using this device, a nearly parallel ultraviolet ray beamis obtained. Black bars of FIG. 31 represent the spectrum of theultraviolet rays.

As the glass substrate 12(14), an OA2 glass substrate manufactured byAsahi Glass Co is used. This glass substrate is made of a borosilicateglass or a so-called alkali-free glass, and exhibits ultraviolet raytransmission characteristics similar to those shown in FIG. 31.

The energy of ultraviolet rays increases as the wavelength becomesshorter, and light of 250 nm is more effective in reforming thealignment layer 20(24). It is therefore desired to use the source oflight containing components around 250 nm. Even when use is made of asource of light not containing components around 250 nm, the ultravioletrays contain components of a wavelength region effective in reformingthe alignment layer. In such a case, there should be employed a glasssubstrate which absorbs light of such a wavelength region to accomplisha desired object.

The source of light emitting ultraviolet rays will be, for example, ahigh-pressure mercury lamp, a low-pressure mercury lamp, a xenon lamp,etc., and there should be used a glass substrate that absorbs lighteffective in reforming the alignment layer. For example, when light near250 nm is effectively used, it is recommended to use a soda-lime glassas the glass substrate to accomplish such an effect.

Examples of the combination of the source of light and the glasssubstrate include a combination of the high-pressure mercury lamp andthe soda-lime glass, and a combination of the xenon lamp and thesoda-lime glass or the borosilicate glass or the alkali-free glass. Whenthe substrate 12(14) is made of a plastic, it is desired that thesubstrate material is selected from polycarbonate, polyethylene andpolystyrene.

FIGS. 32 to 34 illustrate a further embodiment of the present invention.This embodiment is to improve the feature for realizing a plurality ofdifferent alignments by irradiating the alignment layer 20(24) withultraviolet rays in an inclined direction as in the embodiment shown inFIGS. 16 to 25.

FIG. 32 illustrates the alignment treatment for the alignment layer20(24). FIG. 33 illustrates a state where the liquid crystal moleculesare aligned relative to the alignment layer 20(24) when the thusalignment-treated alignment layer 20(24) is used for the liquid crystaldisplay device (FIG. 16). FIG. 34 shows a mask used for the alignmenttreatment of FIG. 32. The liquid crystals 16 have a dielectric constantof negative anisotropy, and the alignment layer 20(24) is composed of apolyimide having a vertical aligning property.

Referring to FIGS. 32 and 33, the alignment layer 20(24) includes aplurality of regions 78A and 78B sectionalized into stripes. The region78A includes a plurality of unit regions P that are continuous to eachother, and the region 78B includes a plurality of unit regions Q thatare continuous to each other. Referring to the X-axis and Y-axisorthogonal to each other, the regions 78A and 78B are extending parallelto the X-axis. The ultraviolet rays 68A are obliquely incident to theregion 78A of the alignment layer 20(24) in a direction parallel to theX-axis. As a result, the liquid crystal molecules 16A in the region 78Aare pretilted toward the upper side in FIG. 33. On the other hand, theultraviolet rays 68B are obliquely incident to the region 78B of thealignment layer 20(24) in a direction parallel to the X-axis. As aresult, the liquid crystal molecules 16B in the region 76B are pretiltedtoward the lower side in FIG. 33. As described above, however, theliquid crystal molecules 16A in the region 78A may be pretilted towardthe lower side in FIG. 33 and the liquid crystal molecules 16B in theregion 78B may be pretilted toward the higher side in FIG. 33.

Referring to FIG. 34, the mask 80 is obtained by vaporizing chromium 80Bon a synthetic quartz plate 80A. A portion of chromium 80B works toshut-off light, and a portion between chromium 80B and chromium 80Bserves as an opening. Chromium 80B extends in the direction of X-axis.The width of chromium 80B and the width of opening in the mask 80 are inagreement with the width of the regions 78A and 78B. Referring to FIG.32, therefore, the ultraviolet rays 68A are projected, using the mask 80and placing the openings of the mask 80 on the regions 78A. The mask 80is then displaced by one pitch in the lateral direction and, then, theultraviolet rays 68B are projected, placing the openings of the mask 80on the regions 78B.

Here, as the method of irradiation with ultraviolet rays 68A and 68B,there are a method of irradiation with ultraviolet rays in the twodirections by providing two lamps for projecting ultraviolet rays, and amethod of irradiation with ultraviolet rays using one lamp and turningthe mask and the substrate together by 180 degrees.

FIG. 37 shows an example where two lamps 82A and 82B are used. The firstlamp 82A is used for the irradiation with ultraviolet rays of the firsttime, and the second lamp 82B is used for the irradiation withultraviolet rays from the opposite direction in the second time. Betweenthe first time of irradiation with ultraviolet rays and the second timeof irradiation with ultraviolet rays, in this case, the mask 80 isdisplaced in the direction (of an arrow) perpendicular to the directionof stripes of the regions 78A and 78B and by a distance equal to thewidth of the stripe.

FIG. 38 illustrates an example using a lamp 82. In this case, after thefirst time of irradiation with ultraviolet rays, the substrate 12(14) orboth the substrate and the mask 20(24) are turned by 180 degrees (asindicated by an arrow), so that the region that was not irradiated withultraviolet rays the first time is now irradiated with ultraviolet raysthe second time. In this case, both the substrate 12(14) and the mask 80are turned by 180 degrees, the position of the mask is displacedrelative to the substrate, and the irradiation with ultraviolet rays ofthe second time is effected. It is also allowable to displace theposition of the substrate relative to the mask, turn the position of thesource of ultraviolet rays by 180 degrees, and, then, project theultraviolet rays.

FIG. 35 illustrates the case where the ultraviolet rays 68 are projectedin the direction of the Y-axis of the mask 80. In this case, theultraviolet rays 68 proceed in a direction perpendicular to the chromium(light shut-off portion) 80B of the mask 80. When the distance betweenthe mask 80 and the alignment layer 20(24) is deviated by d′, therefore,the position of exposure on the alignment layer 20(24) is deviated by d″in the transverse direction. On the other hand, when the ultravioletrays 68 are projected in the direction of X-axis of the mask 80 as shownin FIGS. 32 and 34, the position of exposure on the alignment layer20(24) is not deviated in the transverse direction despite the distancebetween the mask 80 and the alignment 20(24) is deviated by d′.

In the example of FIG. 24, a plurality of different alignments arerealized by using a single mask 74 and by obliquely projecting theultraviolet rays in the opposite directions. According to this method,however, if the distance between the mask 74 and the alignment layer20(24) is deviated by, for example, 10 μm, the position of exposure onthe alignment layer 20(24) is likely to be deviated by 10 μm in thetransverse direction. As the glass substrate 12(14) becomes large,furthermore, the glass substrate 12(14) may be deflected due to its ownweight or due to the weight of the mask 74, causing the same problem aswhen the distance between the mask 74 and the alignment layer 20(24) isdeviated. For example, it has been known that a chromium mask measuring400×500 mm having a thickness of 20 mm is deflected by about 10 μm atthe center. This problem can be solved in the way described withreference to FIGS. 32 to 34.

FIG. 36 is a view illustrating a relationship between the angle ofirradiation with ultraviolet rays 68A, 68B and the pretilt angle that isrealized. The angle of irradiation is taken in a direction perpendicularto the alignment layer 20(24). When the ultraviolet rays 68A and 68B areincident in an inclined direction of 45 degrees relative to thealignment layer 20(24), it is possible to stably realize a pretilt angleof 88 degrees. FIG. 32 illustrates the irradiation with ultraviolet rays68A, 68B in an inclined direction of 45 degrees relative to thealignment layer 20(24).

The stability of alignment decreases as the angle of irradiation withultraviolet rays deviates from 45 degrees. Therefore, even when it isdesired to realize a pretilt angle of, for example, 88 degrees, it oftenbecomes difficult to realize the pretilt angle of 88 degrees. To stablyrealize a desired pretilt angle, therefore, it is desired that the angleof irradiation is from 20 degrees to 70 degrees and, more preferably,from 30 degrees to 60 degrees. The alignment remains most stable anduniform when the angle is 45 degrees.

FIG. 39 illustrates a case where a pair of substrates 12 and 14 arestuck together such that the directions of stripes of the regions 78Aand 78B of the alignment layers 20 and 24 are perpendicular to eachother. In this case, four kinds of domains (alignment regions) J, K, Land M are formed as shown in FIG. 40. In FIG. 40, the members shown bysolid nails denote liquid crystal molecules in front of the surface ofthe paper and the members shown by broken nails denote liquid crystalmolecules at the back of the surface of the paper. Thus, there arerealized a total of four kinds of liquid crystal alignments includingtwo start points of turn and two directions of turn, the angle of twistbeing 90 degrees in each of the domains J, K, L and M.

When no voltage is applied, the liquid crystal molecules aresubstantially vertically erect on the surface of the substrate at apretilt angle of 88 degrees. When a voltage is applied, however, theliquid crystal molecules turn and lie down. The angles of azimuth of theturn are different by 90 degrees relative to one another at the centerof the turn. That is, in the domain J, the liquid crystal twistsleftwards (in the drawing, it may appear to be twisted rightwards,which, however, is defined to twists leftwards in the field of liquidcrystal panels), and the start point is the lower side in the drawing.In the domain L, the liquid crystal twists rightwards, and the startpoint is the upper side in the drawing.

When the voltage is applied, the liquid crystal molecules intermediatelypositioned between the two substrates are tilted toward the left lowerside in the domain J as indicated by an arrow a, toward the right lowerside in the domain K as indicated by an arrow b, toward the left upperside in the domain L as indicated by an arrow c, and toward the rightupper side in the domain M as indicated by an arrow d. Each pixelincludes the four domains J, K, L and M. The viewing anglecharacteristics differ in the four domains J, K, L and M, and viewingangle characteristics which are favorable as a whole are obtained due tothe mixture of different viewing angle characteristics.

FIG. 41 illustrates a case where a pair of substrates 12 and 14 arestuck together such that the directions of stripes of the regions 78Aand 78B of the alignment layers 20 and 24 are parallel to each other. Inthis case, the tilted directions of the liquid crystal are the same inthe opposing portions of the upper and lower substrates. Upon arrangingthe substrates that the region 78A of the upper substrate is opposed tothe region 78B of the lower substrate, the tilted directions of theliquid crystal become opposite to each other in the opposing portions ofthe upper and lower substrates. In the latter case, the liquid crystalis tilted uniformly and in one direction (+X-direction) in that regionupon the application of the voltage. In the other region of the stripe,the liquid crystal is still tilted in one direction, but the directionof azimuth is in the −X-direction. Thus, the alignment can be dividedinto two.

Here, when the alignment is simply divided into two kinds, it ispossible to employ a constitution in which the alignment layer 24 of onesubstrate only is irradiated with ultraviolet rays through the mask 80but the alignment layer 20 of the substrate of the opposite side is notirradiated with ultraviolet rays, as shown in FIG. 42. In this case, thenumber of times of irradiation with ultraviolet rays can be decreasedthough the stability of alignment is deteriorated to some extent.

The embodiments will be further described. Use is made of a verticalalignment layer having alkyl side chains. The alignment layer is appliedby spin-coating and is fired at 180° C. A striped mask 80 is prepared,and the ultraviolet rays are projected in an inclined manner in thedirection of azimuth of the stripe. The ultraviolet rays that aredirected nearly in parallel are projected by using a mercury-xenon lampof the short-arc type.

It is desired that the central wavelength of the irradiated ultravioletrays is around 250 nm. When the film is treated using ultraviolet rays,string-like grooves are not formed in the surface of the alignment layerunlike that when the surface of the alignment layer is rubbed. Here,different alignments are realized by using the mask 80, and a pluralityof regions of different alignments are formed in each pixel. The regionshaving different alignments may be formed in any number irrespective ofwhether there are two kinds or four kinds of alignments in the regions.For instance, if the pitch among the regions is very much smaller thanthe pitch among the pixels, then, no attention needs be given to anypositioning deviation.

The ultraviolet rays are projected from the right in FIG. 37 through themask. The optimum angle of irradiation with ultraviolet rays is 45degrees. The film is oriented at angles of 30 degrees and 60 degrees,too, but an optimum stability of alignment and an optimum uniformity ofalignment are accomplished when the angle is 45 degrees. Next, theposition of the mask is deviated by one-half the pitch of the stripe,i.e., by the width of the stripe in a direction perpendicular to thedirection of the stripe of the mask. That is, the same mask is used, andthe ultraviolet rays are obliquely projected from a direction oppositeto the direction of projection of ultraviolet rays of the first time.

FIG. 43 is a diagram illustrating a relationship between the pixelformed in the substrates 12, 14 and the alignment layers 20, 22 havingregions 78A, 78B that are alignment-treated as shown in FIGS. 39 and 40.As described above, FIGS. 39 and 40 illustrate that each pixel has fourdifferent domains (alignment regions) J, K, L and M in which the liquidcrystal molecules are directed to four directions a, b, c and d at anangle of 90 degrees relative to each other.

The arrangement of FIG. 43 further improves the constitution of FIGS. 39and 40. Here, each pixel includes the display portion C and one-half ofthe non-display portion D of FIGS. 1 to 3 (a black matrix is divided ata center between the neighboring two pixel electrodes 18). That is, thesurfaces of the substrates 12 and 14 are simply separated by vertical,horizontal and diagonal lines. Accordingly, each pixel has a nearlyrectangular shape, and the direction of the stripes forming the regions78A and 78B is at an angle of 45 degrees with respect to the side of therectangle.

When each pixel is divided into four domains J, K, L and M, each domaintypically has a shape analogous to the shape of the pixel and a sizeone-fourth the size of the pixel, as shown in FIG. 45. In this case, asshown in FIG. 46 however, when the position of exposure is deviated inirradiating the alignment layers 20, 24 with ultraviolet rays, the fourregions are partly concealed by the bus line or the black matrix,whereby the ratio of the regions of the pixel decrease and otherportions become relatively large to deteriorate the viewing anglecharacteristics. When the ultraviolet rays are projected in an inclineddirection, therefore, it becomes necessary to more correctly positionthe mask and the work in addition to employing proximity exposure. Inthis case, the apparatus tends to become bulky. Or, an extended periodof time is required for accomplishing the positioning adverselyaffecting the throughput.

The constitution of FIG. 43 is intended to solve this problem andincludes the stripe pattern of the mask 80 for projecting ultravioletrays which is obliquely directed with respect to the arrangement of thepixels. The inclined angle and the width of the stripe (width of theregion 78A or 78B) are so selected that not less than eight domains J,K, L and M are at least partly included in each pixel. Therefore, evenif the position of exposure is deviated at the time of irradiating thealignment layers 20, 24 with ultraviolet rays, the domains J, K, L and Mare present at a constant rate at all times, and the viewing anglecharacteristics are not deteriorated.

Desirably, the direction of the stripes (direction in which the regions78A and 78B extend) is set to define an angle of 45 degrees with respectto the side of a rectangle of the pixel. When the width of the stripe isdenoted by W and the pitch of the rectangular pixel of the short side isdenoted by p, there exists a relation W=(√{square root over (2)})/3×p.This means that the pitch p of the rectangular pixel of the short sideis equal to three stripe widths (widths of three regions 78A, 78B) 3W.

This embodiment employes the TFT-type liquid crystal panel. The threepixels RGB constitute a display unit. The pitch of the pixel is 300 μmin a set of RGB pixels, and each of the pixels RGB has a size of 100μm×300 μm. First, a vertically aligning type polyimide is applied to thesubstrates 12 and 14 to form opposing alignment layers. Then, the TFTsubstrate 12 is irradiated with generally parallel ultraviolet raysthrough the mask 80. Here, use is made of the striped mask 80 having astripe width of 100 μm×√{square root over (2)}÷3≈47.14 μm. The mask iscarefully designed such that the direction of the stripes is 45 degreeswith respect to the direction of the pixel, and the ultraviolet rays areprojected at an inclined angle of 45 degrees in the azimuth directionparallel to the stripes.

Next, the mask 80 is displaced in a direction perpendicular to thestripes by the width of the stripe, and the ultraviolet rays areprojected at an inclined angle of 45 degrees in the azimuth directionparallel to the stripe but opposite to the direction in which theultraviolet rays were projected in the previous time. Therefore, thealignments are, first, obtained as shown in FIG. 33. Next, the colorfilter substrate 14 is irradiated with ultraviolet rays in the samemanner. Here, however, the ultraviolet rays are projected in a mannerthat the direction of the strips is 90 degrees with respect to thedirection of projection of ultraviolet rays upon the TFT substrate 12,such that a positional relationship shown in FIG. 39 is established whenthe color filter substrate 14 and the TFT substrate 12 are stucktogether (assembled).

The pair of substrates 12 and 14 having the thus obtained alignments arestuck together. The constitution of FIG. 43 is thus obtained. Each pixelincludes four kinds of domains J, K, L and M, and each pixel includesabout twenty domains J, K, L and M. A series of domains M, K, J and Lare present in a complete form in each pixel, other domains J′ and M′are positioned on the data bus line of the left side, and other domainsL′ and K′ are positioned on the data bus line of the right side.

FIG. 44 illustrates a state deviated from the state of FIG. 43. Evenwhen the position of exposure is deviated, the ratio of the regionsoccupying the pixel can be kept almost unchanged. For instance, thedomain J in a circle positioned on the lower side has a large area inFIG. 43 but has a small area in FIG. 44. On the other hand, the domain Jin a circle positioned on the upper side has a small area in FIG. 43 buthas a large area in FIG. 44. In bringing the mask into match with thework for optical alignment, therefore, all that is required is simply toset an angle of 45 degrees, and no attention need be given to thepositional relationship. The loss becomes nearly the same in everyregion when the stripe has a width of (√{square root over (2)})/3×p.Even when the position is deviated, therefore, the effect consequentlydecreases.

The ultraviolet rays can be projected irrespective of the positionalrelationship between the mask and the substrate, and, hence, no time isrequired for positioning, the apparatus can be simplified, and thethroughput is improved. In the constitution of FIG. 45, for example, thepositioning requires a time of from 15 to 30 seconds. The four kinds ofregions have different visual angle characteristics which arecomplementary to one another, making it possible to obtain favorablevisual angle characteristics.

FIGS. 47A to 59 illustrate a further embodiment of the presentinvention. FIG. 47A shows the alignment treatment effected byirradiating ultraviolet rays in an inclined direction, similar to thecase of FIG. 32. In this example, the parallel ultraviolet rays 68 areirradiated to the entire surface of the alignment layer 20 in aninclined direction at the angle of 45 degrees with respect to thealignment layer 20. The alignment layer 20 is shown such that itincludes a plurality of divided striped regions 78A and 78B, similar tothe case of FIG. 32, but in the stage of FIG. 47A, the ultraviolet rays68 are irradiated to the alignment layer 20 in the single direction, sothe alignment layer 20 is not yet divided into a plurality of regions78A and 78B. A plurality of regions 78A and 78B are to be divided inthis manner at the later stage, and the alignment layer 20 isconveniently shown to be divided in FIG. 47A for clarity of description.

FIG. 48A shows the liquid crystal molecules aligned relative to thealignment layer 20 when the alignment layer 20 is assembled into aliquid crystal display device. In this case too, a plurality of regions78A and 78B are conveniently shown. The liquid crystal molecules 16A and16B (the regions 78A and 78B) near the alignment layer 20 pretilt at asubstantially constant pretilt angle with respect to the alignment layer20. The used liquid crystal 16 has a negative dielectric constant, andthe alignment layer 20(24) is used polyimide having a vertical aligningproperty.

FIG. 47B shows the further alignment treatment effected after the stepof FIG. 47A. Here, a mask 80, which may be similar to that shown in FIG.34, for example, is used and the alignment layer 20 is irradiated withthe ultraviolet rays in an inclined direction through the mask 80. Themask 80 has permeable portions 80A and impermeable portions 80B. Theregion 78A of the alignment layer 20 is a portion at which theultraviolet rays 68 passing through the permeable portion 80A of themask 80 fall on the alignment layer 20, and the region 78B is a portionof the alignment layer 20 at which the ultraviolet rays 68 do not fallon the alignment layer 20 since the ultraviolet rays 68 are blocked bythe impermeable portion 80B of the mask 80.

FIG. 48B shows the liquid crystal molecules aligned relative to thealignment layer 20 when the alignment layer 20 is assembled into aliquid crystal display device. When the alignment of the liquid crystalis realized by irradiating the vertical alignment layer 20 with theultraviolet rays, the greater the amount of the irradiation of theultraviolet rays is, the greater the energy for destroying the verticalaligning function becomes, and the smaller the pretilt angle relative tothe alignment layer 20 is. Since the region 78A of the alignment layer20 is twice irradiated with the ultraviolet rays and the region 78B ofthe alignment layer 20 is irradiated with the ultraviolet rays one time,the dose of the ultraviolet rays to the region 78A is greater than thatto the region 78B.

Therefore, the pretilt angle of the liquid crystal molecules 16A nearthe region 78A of the alignment layer 20 is smaller than the pretiltangle of the liquid crystal molecules 16B near the region 78B of thealignment layer 20. As a result, upon the application of voltage, theliquid crystal molecules 16A near the region 78A of the alignment layer20 change from the generally vertical position to the generallyhorizontal position easier than the liquid crystal molecules 16B nearthe region 78B of the alignment layer 20 change, and the thresholdvoltage for driving the liquid crystal at the region 78A becomes lowerthan the threshold voltage for driving the liquid crystal at the region78B.

FIGS. 49A and 49B show the alignment treatment effected to the otheralignment layer 24, in a similar manner to the alignment layer 20. InFIG. 49A, the parallel ultraviolet rays 68 are irradiated to the entiresurface of the alignment layer 24 in an inclined direction at the angleof 45 degrees with respect to the alignment layer 24. The ultravioletrays 68 are irradiated to the alignment layer 24 in the direction(Y-direction) perpendicular to the stripes defining a plurality ofregions 78A and 78B in FIG. 49A, while the ultraviolet rays 68 areirradiated to the alignment layer 20 in the direction (X-direction)parallel to the stripes defining a plurality of regions 78A and 78B inFIG. 47A.

Therefore, the liquid crystal molecules 16A and 16B near the regions 78Aand 78B of the alignment layer 24 pretilt at a substantially constantpretilt angle with respect to the alignment layer 24 in the direction ofthe Y-axis, as shown in FIG. 50A.

In FIG. 49B, the alignment layer 24 is irradiated with the ultravioletrays 68 in an inclined direction through the mask 80. In this case too,the pretilt angle of the liquid crystal molecules 16A near the region78A of the alignment layer 20 is smaller than the pretilt angle of theliquid crystal molecules 16B near the region 78B of the alignment layer20, as shown in FIG. 50B. As a result, upon the application of voltage,the liquid crystal molecules 16A near the region 78A of the alignmentlayer 20 change from the generally vertical position to the generallyhorizontal position easier than the liquid crystal molecules 16B nearthe region 78B of the alignment layer 20 change.

The pretilt direction of the liquid crystal molecules relative to thealignment layer 20 in FIG. 48B is the X-direction, and the pretiltdirection of the liquid crystal molecules relative to the alignmentlayer 24 in FIG. 50B is the Y-direction. Therefore, when the alignmentlayer 20 in FIG. 48B and the alignment layer 24 in FIG. 50B aresuperimposed together as they are, the liquid crystal twists 90 degrees.Here, it is defined that the liquid crystal molecules lie down inY-direction, but it is also possible to define that the liquid crystalmolecules lie down in X-direction.

FIG. 51 shows the thus fabricated liquid crystal display device 10. Inone alignment layer 20 (or 24), the doze of the irradiation of theultraviolet rays to the region 78A is different for that to the region78B. In addition, the dose of the irradiation of the ultraviolet rays tothe region 78A (or 78B) in one alignment layer 20 is substantiallyidentical to that to the corresponding region 78A (or 78B) in the otheralignment layer 24.

Therefore, in the region 78A, the pretilt angle of the liquid crystalmolecules near the alignment layer 20 is δ, and the pretilt angle of theliquid crystal molecules near the alignment layer 24 is also δ. Thepretilt angles on both alignment layers are the same. Similarly, in theregion 78B, the pretilt angle of the liquid crystal molecules near thealignment layer 20 is γ, and the pretilt angle of the liquid crystalmolecules near the alignment layer 24 is also γ. The pretilt angles onboth alignment layers are the same. Therefore, the symmetry of thebehavior of the liquid crystal is maintained in the respective regions78A and 78B of the opposed alignment layers 20 and 24.

FIG. 54 shows the relationship between the applied voltage and thetransmittance of the liquid crystal display device 10 of FIGS. 47A to51. The curve 79A shows the relationship between the applied voltage andthe transmittance of the region 78A, and the curve 79B shows therelationship between the applied voltage and the transmittance of theregion 78B. The curves 79A and 79B have lobes P and P′. If the liquidcrystal display device is constructed by elements having the featurecorresponding to only one of the regions 78A and 78B, there is a problemthat a display image reverses from white to black and vice versa at theportion of the lobes P and P′ when the display is viewed in an inclineddirection.

In this embodiment, the two regions 78A and 78B form one pixel. Byarranging so that one pixel includes at least two regions 78A and 78Bhaving different threshold voltages, it is possible to solve thatproblem that a display image reverses from white to black and vice versaat the portion of the lobes P and P′ when the display is viewed in aninclined direction. That is, in the region 78A where the dose of theirradiation of the ultraviolet rays is greater, the pretilt angle δ issmaller, so that the liquid crystal molecules easily fall down towardthe alignment layers 20 and 24 and the threshold voltage is smaller. Onthe other hand, in the region 78B where the dose of the irradiation ofthe ultraviolet rays is smaller, the pretilt angle γ is greater and theliquid crystal molecules are aligned generally vertically relative tothe alignment layers 20 and 24, so that the liquid crystal molecules donot easily fall down toward the alignment layers 20 and 24 and thethreshold voltage is greater.

When the voltage is applied to the liquid crystal display device 10 andthe applied voltage becomes higher than a certain threshold voltagecorresponding to a certain gray scale value in the region 78A, and inthe case where the region 78A of the liquid crystal display device 10 isviewed in an inclined direction, a display image reverses from white toblack and vice versa. However, the applied voltage does not reach acertain threshold voltage corresponding to that gray scale value in theother region 78B and a display image does not reverse from white toblack and vice versa in the other region 78B. In the present invention,since the two regions 78A and 78B form one pixel, the display imageshaving the features of the different threshold voltages are mixed, andthe image reversing tendency is mitigated over a whole pixel. The curve79C shows the relationship between the applied voltage and thetransmittance in the compound pixel, in which the bending portions arereduced compared to the curves 79A and 79B.

There are conventional techniques in which one pixel is divided into tworegions having different threshold voltages. For example, FIG. 55 showsan example of a conventional threshold voltage division. In FIG. 55, adielectric member 90 is arranged in one region so that the voltage isnot efficiently applied in that region to increase the threshold voltagefor the liquid crystal itself, to thereby realize two regions havingdifferent threshold voltages. However, in this case, in thisconstitution, the step for providing the dielectric member 90 is addedso that the manufacturing process becomes complex, resulting in areduced yielding and an increased cost. In addition, a necessary voltagelevel is increased by the provision of the dielectric member 90.

According to this embodiment, it is possible to realize the alignment ofthe liquid crystal and to form a plurality of regions having differentthreshold voltages, by a relatively simple means such as the irradiationof the ultraviolet rays, and without using rubbing (therefore, withoutany groove-like traces which may otherwise formed in the surfaces of thealignment layers 20 and 24 by rubbing). Therefore, it is possible toimprove the viewing angle characteristics of the liquid crystal displaydevice without any increase in the production cost.

Preferably, as shown in FIG. 51, and as described above, in each of thetwo regions 78A and 78B of one pixel, the dose of the irradiation of theultraviolet rays to one region of one alignment layer is substantiallyidentical to that to the corresponding region of the other alignmentlayer. Therefore, in the region 78A, the pretilt angle of the liquidcrystal molecules near the alignment layer 20 and the pretilt angle ofthe liquid crystal molecules near the alignment layer 24 are equally δ,and in the region 78B, the pretilt angle of the liquid crystal moleculesnear the alignment layer 20 and the pretilt angle of the liquid crystalmolecules near the alignment layer 24 are equally γ.

FIG. 52 shows a variant example of the alignment treatment. In FIG. 52,in the region 78B, the pretilt angle of the liquid crystal moleculesnear the alignment layer 20 is γ and the pretilt angle of the liquidcrystal molecules near the alignment layer 24 is 90 degrees(substantially no pretilt). In this case, when the voltage is applied,the liquid crystal molecules as a whole fall down toward the surfaces ofthe alignment layers according to the pretilt angle of the liquidcrystal molecules near the alignment layer 20. In the other region 78A,the pretilt angle of the liquid crystal molecules near the alignmentlayer 20 and the pretilt angle of the liquid crystal molecules near thealignment layer 24 are equally δ. In this case, the alignment layer 20is treated for alignment in a manner as described with reference toFIGS. 47A and 47B, but the alignment layer 24 is treated for alignmentusing the mask 80 one time.

FIG. 53 shows a variant example of the alignment treatment. In FIG. 53,in the region 78A, the pretilt angle of the liquid crystal moleculesnear the alignment layer 20 is γ and the pretilt angle of the liquidcrystal molecules near the alignment layer 24 is δ. In the other region78B, the pretilt angle of the liquid crystal molecules near thealignment layer 20 is δ and the pretilt angle of the liquid crystalmolecules near the alignment layer 24 is δ. In addition, the pretiltdirection on the alignment layer 20 is constant and the pretiltdirection on the alignment layer 24 is constant. In this constitution,the tilting direction of the liquid crystal in the region 78A is inreverse to the tilting direction of the liquid crystal in the region78B, so that a good viewing angle characteristics can be realized.

FIGS. 56A and 56B show a further variant example of the alignmenttreatment. This alignment treatment is carried out according to stepsreverse to the steps of FIGS. 47A and 47B. That is, as shown in FIG.56A, the alignment layer 20 is irradiated with ultraviolet rays usingthe mask 80 so that the dose of the irradiation of the ultraviolet raysto the region 78A is different from the dose of the irradiation of theultraviolet rays to the region 78B. Then, as shown in FIG. 56B, thewhole surface of the alignment layer 20 is irradiated with ultravioletrays in the single direction without using the mask 80. The otheralignment layer 24 is then treated according to the steps in reverse tothe steps of FIGS. 49A and 49B. As result of these alignment treatments,it is possible to obtain a liquid crystal display device similar to thatshown in FIG. 51.

FIGS. 57A and 57B show a further variant example of the alignmenttreatment. This alignment treatment is carried out according to thesteps similar to the steps of FIGS. 47A and 47B. That is, as shown inFIG. 57A, the whole surface of the alignment layer 20 is irradiated withultraviolet rays in the single direction without using the mask 80.Then, as shown in FIG. 57B, the alignment layer 20 is irradiated withultraviolet rays using the mask 80 so that the dose of the irradiationof the ultraviolet rays to the region 78A is different from the dose ofthe irradiation of the ultraviolet rays to the region 78B. The angle ofthe irradiation of the ultraviolet rays in FIG. 57A is not identical tothe angle of the irradiation of the ultraviolet rays in FIG. 57B.

In FIG. 57A, the ultraviolet rays are irradiated to the alignment layer20 at the angle of 45 degrees relative to the alignment layer 20, but inFIG. 57B, the ultraviolet rays are irradiated to the alignment layer 20at the angle of 90 degrees relative to the alignment layer 20. Theirradiation of the ultraviolet rays at the angle of 45 degrees isnecessary for realizing the alignment with a pretilt angle. Then, thealignment treatment is once carried out to realize the alignment with apretilt angle, it is not necessary to irradiate the alignment layer 20with the ultraviolet rays at the angle of 45 degrees, it is onlynecessary to irradiate the alignment layer 20 with the ultraviolet raysto change the pretilt property by changing the irradiation energy of theultraviolet rays. This is also true for the alignment layer 24. Inaddition, the step of FIG. 57A is first carried out and the step of FIG.57B is then carried out in this embodiment, but it is also advisable tocarry out the step of FIG. 57B first and then the step of FIG. 57A.

In the above embodiments, the mask 80 has permeable portions 80A andimpermeable portions 80B. The impermeable portions 80B can be thosewhich can perfectly block the ultraviolet rays. But it is also possiblethat the impermeable portions 80B can be those which can partly blockthe ultraviolet rays and partly allow some of the ultraviolet rays topass therethrough. In addition, it is not necessary that the permeableportions 80A and that impermeable portions 80B are completely segmented,but the permeable portions 80A and that impermeable portions 80B can beconstructed so that the transmitting property indefinitely changes alongthe permeable portions 80A and that impermeable portions 80B. Theirradiation of the ultraviolet rays is carried out two times in theabove described embodiments, but it is possible to carry out theirradiation of the ultraviolet rays several times.

FIG. 58 shows a further example in which the alignment layer 20(24) isirradiated with the ultraviolet rays using the mask 80. The mask 80 haspermeable portions 80A and impermeable portions 80B. The mask 80 wasarranged close to and parallel to the alignment layer 20(24) in theembodiment of FIGS. 47A-47B, 49A-49B, 56A-56B, and 57A-57B, but the mask80 is not arranged parallel to the alignment layer 20(24) in FIG. 58.For example, the mask 80 is arranged at the angle of 45 degrees relativeto the alignment layer 20(24).

In order to provide regions 78A and 78B having different thresholdvoltages, it is necessary that the dose of the irradiation of theultraviolet rays to one region is different from the dose of theirradiation of the ultraviolet rays to another region. In this sense,there is no problem if the dose of the irradiation of the ultravioletrays continuously changes. There is a case where the dose of theirradiation of the ultraviolet rays continuously changes since theliquid crystal molecules in the regions 78A and 78B fall down in thesame direction. In this regard, it is not necessary that the dose of theirradiation of the ultraviolet rays is discontinuously controlled by themask 80. Therefore, the mask 80 can be arranged at a distance from thealignment layer 20(24) and at an angle relative to the alignment layer20(24), as shown in FIG. 58. In this case, it is possible to use anexisting ultraviolet ray irradiating machine such that the substratehaving the alignment layer 20(24) to be irradiated is simply arranged atan angle relative to the machine.

In FIG. 58, the ultraviolet rays 68 pass through the permeable portions80A and are blocked by the impermeable portions 80B. The ultravioletrays 68 are supplied as parallel beams, but they are not perfectlyparallel beams. The ultraviolet rays 68 include light components 68Cwhich are made incident to the mask 80 in an inclined direction, so thatthe light components 68C pass through the permeable portions 80A tospaces below the impermeable portions 80B and are made incident toportions of the alignment layer 20(24) that are to be covered by theimpermeable portions 80B.

FIG. 59 shows a further example in which the alignment layer 20(24) isirradiated with the ultraviolet rays. In this example, the mask 80 isomitted in the drawings, but the mask 80 is used in the firstirradiation of the ultraviolet rays and the second irradiation of theultraviolet rays, and the dose of the irradiation of the ultravioletrays is changed in each of the regions 78A and 78B and in the first andsecond irradiation of the ultraviolet rays. For example, the region 78Aof the alignment layer 20 is irradiated with the ultraviolet rays, atthe dose of 3.0 (optional units), and the region 78B of the alignmentlayer 20 is irradiated with the ultraviolet rays at the doze of 1.5. Onthe other hand, the region 78A of the alignment layer 24 is irradiatedwith the ultraviolet rays at the doze of 2.0 (optional unit), and theregion 78B of the alignment layer 24 is irradiated with the ultravioletrays at the doze of 1.0.

If the alignment layers 20 and 24 are superimposed one on the other, asshown in FIG. 59, four regions are formed in which the sums of the dosesin the opposing alignment layers 20 and 24 in these regions are 2.5(1+1.5), 3.5 (2.0+1.5), 4.0 (1+3.0), and 5.0 (2.0+3.0). In this way, itis possible to establish four characteristics having different thresholdvoltages, and to prevent the occurrence of the reversal of a displayimage from white to black and vice versa.

FIGS. 60 to 66 shows a further embodiment of the present invention. FIG.60 shows a portion of the liquid crystal display device 10 correspondingto one pixel, and FIG. 61 shows the alignment of the liquid crystal inone pixel portion of the liquid crystal display device 10. The alignmentof the liquid crystal in FIG. 61 is identical to that shown in FIG. 40,and one pixel includes four regions J, K, L, and M. The four regions J,K, L, and M are divided by a boundary line which extends, as a cross,across one pixel.

As shown in FIG. 60, the liquid crystal display device 10 includes aliquid crystal 16 between the pair of substrates 12 and 14, similar tothe above described embodiments. Each substrate includes an electrode(electrode layer) and an alignment layer. The alignment layer isalignment-treated to realize an alignment with a pretilt angle byirradiation with the ultraviolet rays. The liquid crystal display device10 also includes an active matrix comprising the pixel electrodes 18,drain bus lines 30, gate bus lines 32 and TFTs 34. The liquid crystaldisplay device 10 also includes a storage capacity electrode 40.

The storage capacity electrode 40 passes nearly through the center ofthe pixel electrode 18 and extends vertically and horizontally as across. That is, the storage capacity electrode 40 establishes itsfundamental function and is formed as a shading layer covering thecrosslike boundary line which divides the pixel into four regions J, K,L, and M. The storage capacity electrode 40 is formed from chrome, anddoes not allow light to pass therethrough.

FIG. 62 is a view illustrating the relationship between the appliedvoltage and the transmittance of the quartered, vertically alignedliquid crystal display device when no storage capacitance electrode isused. The quartered, vertically aligned liquid crystal display devicemakes it possible to realize a wide viewing angle in which a gooddisplay is obtained. In this alignment, like vanes of a windmill, aphenomena has been observed, in the crosswise boundary line dividing thefour regions J, K, L, and M, in that the brightness first considerablyincreases as shown by the point H and subsequently the brightnessdecreases to a stable level, when a white display is produced byapplying a high voltage from the voltage-off condition. It is consideredthat this phenomena occurs because the behavior of the liquid crystalmolecules is not stable at the instant the voltage is applied in thecrosswise boundary line so that the brightness extremely increases andsubsequently the transverse interaction between the liquid crystalmolecules begins to act so that the brightness settles to a stablevalue.

In a conventional liquid crystal display device having a storagecapacitor electrode or an auxiliary capacitor electrode (like 40) whichextends in the horizontal direction only, a horizontal portion in thecrosswise shining portion can be covered by the conventional horizontalstorage capacitor electrode (40) and there is no problem regarding thehorizontal shining portion. However, there is a problem in theconventional liquid crystal display device regarding a vertical portionin the crosswise shining portion.

In the present invention, it is possible to eliminate the crosswiseextremely bright portion since the storage capacitor electrode 40 cancover the crosswise boundary line. FIG. 63 is a view illustrating therelationship between the applied voltage and the transmittance of thequartered, vertically aligned liquid crystal display device when thecrosswise storage capacitance electrode 40 is provided. It will beunderstood that the extreme increase in the transmittance in FIG. 62 iseliminated in FIG. 63. In the case where the storage capacitanceelectrode 40 includes the vertically extending portion in addition tothe horizontally extending portion, the horizontally extending portionis narrowed to reduce its area compared to the case where thehorizontally extending portion only is provided and the reduced area isgiven to the vertically extending portion. By this arrangement, it ispossible to eliminate the extremely bright portion, without affectingthe aperture of the display.

FIG. 64 shows an example in which a portion of the shading layer whichcovers the crosswise boundary line dividing the four regions J, K, L isformed by the horizontally extending storage capacitance electrode 40and another portion of the shading layer is formed by a member 28X whichis integral with the black matrix 28. By this arrangement too, it ispossible to eliminate the extremely increasing transmittance.

FIG. 65 shows another example to prevent an occurrence of the extremelybright portion in the crosswise boundary line dividing the four regionsJ, K, L. The liquid crystal display device to which the feature of FIG.65 is applied is constructed such that one pixel has four regions havingdifferent alignments of the liquid crystal divided by a crosswiseboundary line (refer to FIGS. 61 and 62), and includes polarizers 29Aand 29B arranged in the cross-Nicol arrangement (FIG. 2).

FIG. 65 shows that the polarizers 29A and 29B are arranged in thepredetermined directions deviated in the range from 5 degrees to 20degrees relative to the vertical direction 100 and the horizontaldirection 102. That is, the transmission axes of the polarizers 29A and29B are arranged within the ranges I. In addition, FIG. 65 shows thatthe polarizers 29A and 29B are arranged in the predetermined directionsdeviated in the range from 5 degrees to 20 degrees relative to thedirections 104 and 106 of diagonally 45 degrees with respect to thevertical direction 100 and the horizontal direction 102. That is, thetransmission axes of the polarizers 29A and 29B are arranged within theranges J. On contrast, the polarizers 29A and 29B were generallyarranged in the vertical direction 100, the horizontal direction 102, orthe direction 104 or 106 of diagonally 45 degrees.

FIG. 66 shows the relationship between the applied voltage and thetransmittance of the liquid crystal display device when the polarizers29A and 29B are deviated. The curve R shows the characteristics when thetransmission axes of the polarizers 29A and 29B are arranged in thevertical and horizontal directions. This is identical to thecharacteristics of FIG. 62. The curve S shows the characteristics whenthe transmission axes of the polarizers 29A and 29B are deviated by 20degrees with respect to the vertical and horizontal directions. Thecurve T shows the characteristics when the transmission axes of thepolarizers 29A and 29B are deviated by 10 degrees with respect to thevertical and horizontal directions.

It will be understood that the extremely bright point H in the curve Rcan be eliminated in the curves S and T, by the comparison of the curvesS and T with the curve R. In the test, a favorable result is obtained bydeviating the transmission axes of the polarizers 29A and 29B within theabove described range. There good effect is obtained by the deviation offrom 5 degrees to 20 degrees, but it is more preferable to deviate from10 degrees to 15 degrees.

FIG. 67 shows a further embodiment of the present invention. The liquidcrystal display device 10 includes a liquid crystal 16 and spacers 110between a pair of substrates 12 and 14. The spacers 110 are smallspherical members to maintain a constant gap between the pair ofsubstrates 12 and 14. In this embodiment, a vertical aligning treatmentis effected on the surfaces of the spacers 110. It is possible to applya silane coupling agent or a material for a vertical alignment layer onthe surfaces of the spacers 110.

As shown in FIG. 68, it is possible that the liquid crystal moleculesaround the spacers 110 are aligned along the surfaces of the spacers 110(horizontal alignment) if the vertical aligning treatment is noteffected on the surfaces of the spacers 110. In the liquid crystaldisplay device 10 in which a vertical alignment with a pretilt isrealized by irradiating the alignment layers 20 and 24 with ultravioletrays, if a horizontal aligning property exists around the spacers 110,the liquid crystal molecules are controlled by that horizontal aligningforce, and prevented from aligning in the desired vertical direction.Therefore, a problem arises that the display becomes dark.

If the vertical alignment treatment is effected on the surfaces of thespacers 110, on contrast, the liquid crystal molecules are not affectedby such a horizontal aligning force, and the vertical aligning force isrelatively weak, so the liquid crystal molecules can align in thedesired vertical direction. Therefore, a bright display can be realized.This feature can be applied to all the embodiments of the liquid crystaldisplay device 10 in which a vertical alignment with a pretilt angle isrealized by irradiating the alignment layers 20 and 24 with ultravioletrays.

According to the present invention as described above, it is possible toprevent the occurrence of a state where an electric charge remains inlarge amounts near one of the opposing alignment layers, and the imagepreviously displayed remains slightly due to the residual electriccharge even after the voltage is no longer applied. It is furtherpossible to effect the alignment treatment upon the irradiation withultraviolet rays, instead of effecting the rubbing. The alignmenttreatment can also be effected by irradiation with ultraviolet rays incombination with rubbing.

1. A liquid crystal display device comprising: a pair of spaced andopposed substrates; an electrode and an alignment layer formed on onesubstrate and an electrode and an alignment layer formed on the othersubstrate; liquid crystal filled between said pair of substrates; and aplurality of pixels, wherein each pixel has four different alignmentquadrants, with liquid crystal molecules in each consecutive quadrant,in a counter clockwise direction around the center of the pixel, beingoriented at +90 degrees relative to liquid crystal molecule orientationsin the previous quadrant.
 2. The liquid crystal display device accordingto claim 1, wherein each quadrant within a pixel is of approximately thesame size and shape.
 3. A liquid crystal display device according toclaim 1, wherein said alignment layers are treated by irradiation withultraviolet rays using a mask having stripe openings, and in irradiatingthe substrates with ultraviolet rays two times through the stripe mask,the substrate is irradiated with ultraviolet rays a first time and,thereafter the positions of the mask and the liquid crystal panelsubstrates are deviated relative to each other and the substrates areirradiated, through the same mask, with ultraviolet rays a second timefrom a direction opposite to the direction of the ultraviolet rayirradiation of the first time.
 4. A liquid crystal display deviceaccording to claim 1, wherein a liquid crystal having a dielectricconstant of negative anisotropy is used.
 5. A liquid crystal displaydevice according to claim 1, wherein, when the width of the stripe is Wand the length of the short side of the pixel isp, there exists therelationship, W=(√2)/3×p.
 6. The liquid crystal display device accordingto claim 1, wherein the alignment direction of the liquid crystalmolecules in adjacent regions on each substrate is parallel to aboundary of said adjacent regions.
 7. A liquid crystal display devicecomprising: a pair of spaced and opposed substrates; an electrode and avertical alignment layer formed on one substrate and an electrode and avertical alignment layer formed on the other substrate; liquid crystalfilled between said pair of substrates; and a plurality of pixels,wherein each pixel has four different alignment regions, and said fourdifferent alignment regions are formed so that liquid crystal moleculestherein are oriented in four different directions, shifted 90 degreesrelative to each adjacent alignment region.
 8. The liquid crystaldisplay device according to claim 7, wherein the liquid crystalmolecules in said four different alignment regions are aligned in aclockwise orientation around a center of the pixel.
 9. The liquidcrystal display device according to claim 7, wherein the alignmentdirection of the liquid crystal molecules in adjacent regions on eachsubstrate is parallel to a boundary of said adjacent regions.
 10. Aliquid crystal display device according to claim 7, wherein saidalignment layers are treated by irradiation with ultraviolet rays usinga mask having stripe openings, and in irradiating the substrates withultraviolet rays two times through the stripe mask, the substrate isirradiated with ultraviolet rays a first time and, thereafter thepositions of the mask and the liquid crystal panel substrates aredeviated relative to each other and the substrates are irradiated,through the same mask, with ultraviolet rays a second time from adirection opposite to the direction of the ultraviolet ray irradiationof the first time.
 11. A liquid crystal display device according toclaim 7, wherein a liquid crystal having a dielectric constant ofnegative anisotropy is used.
 12. A liquid crystal display deviceaccording to claim 7, wherein, when the width of the stripe is W and thelength of the short side of the pixel is p, there exists therelationship, W=(√2)/3×p.